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(+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene

Base Information Edit
  • Chemical Name:(+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene
  • CAS No.:175890-06-9
  • Molecular Formula:C27H28FeNP
  • Molecular Weight:453.347
  • Hs Code.:
  • Mol file:175890-06-9.mol
(+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene

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Chemical Property of (+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene Edit
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Technology Process of (+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene

There total 1 articles about (+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With BuLi; TMEDA; In diethyl ether; hexane; Ar-atmosphere; dropwise addn. of BuLi (in hexane) to Fe-complex (in Et2O), stirring (room temp., 3 h), addn. of TMEDA and further BuLi, stirring(room temp., 20 h), addn. of excess Ph2PCl at -78°C, refluxing f or 1 h; addn. of aq. Na2CO3, extn. of aq. layer (Et2O), drying combined extracts(MgSO4), solvent removal (vac.), chromy. (SiO2, petroleum ether/Et2O/Et 3N=75:24.7:0.3 to 65:34.8:0.2); five further products (1,1'-PPh2-disubstituted isomers);
DOI:10.1016/0022-328X(95)05849-K
Guidance literature:
In toluene; High Pressure; under N2 atm. soln. Ru complex and ligand in toluene was heated at 130°C for 15 h in Fisher-Porter tube; soln. was evapd. to dryness, residue was triturated with Et2O; elem. anal.;
DOI:10.1021/om060314g
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