Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

Base Information

Chemical Name:Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)
CAS No.:144812-17-9
Molecular Formula:C₂₀H₂₃As₂O₄Re
Molecular Weight:663.45
Hs Code.:

Re(CO)3(OC<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)(C<sub>6</sub>H<sub>4</sub>(As(CH<sub>3</sub>)2)2)

Synonyms:

Suppliers and Price of Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

There total 3 articles about Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 106-44-5
p-cresol

: 138695-29-1
(CO)3(C₆H₄(As(CH₃)2)2)ReOCH₃

: 144812-17-9
Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

Guidance literature:: In benzene; charging a bomb with Re-compound, p-cresol and C6H6; heating at 44°C for 10 h; inert atm.; mechanism discussed;; removal of volatiles under vac.; dissolving in toluene; layering with ether; cooling to -40°C for 2 days; pptn.; filtration; washing with pentane; drying in high vac.; elem. anal.;; Kinetics;
DOI:10.1021/om00027a031

Reference yield: 77.0%

: 138695-26-8
Re(CO)3(P(C₆H₅)3)2(OC₆H₄CH₃)

: 13246-32-7
ortho-phenylenebis(dimethylarsine)

: 144812-17-9
Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

Guidance literature:: In benzene; byproducts: P(C6H5)3; addn. of o-phenylenebis(dimethylarsine) to Re-compound in C6H6; heating in a bomb at 46°C for 12 h; inert atm.;; removal of benzene under vac.; washing with hexane; analytically pure;;
DOI:10.1021/om00027a031

Reference yield:

: 138695-29-1
(CO)3(C₆H₄(As(CH₃)2)2)ReOCH₃

: 140-39-6
1-acetoxy-4-methylbenzene

: 144812-17-9
Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

Guidance literature:: In benzene-d6; byproducts: methyl acetate; NMR tube charged with complex and solvent in a drybox, addn. of tolyl acetate via syringe, kept at room temp. for 12 h; not isolated; 1H-NMR;