[PdMe(1-phenyl-3-sulfanylbut-2-en-1-onate)(diphenyl(o-vinylphenyl)phosphine)]

Base Information

• Chemical Name: [PdMe(1-phenyl-3-sulfanylbut-2-en-1-onate)(diphenyl(o-vinylphenyl)phosphine)]
• CAS No.: 173986-41-9
• Molecular Formula: C₃₁H₂₉OPPdS
• Molecular Weight: 587.03
• Mol file: 173986-41-9.mol

Synonyms:

Chemical Property of [PdMe(1-phenyl-3-sulfanylbut-2-en-1-onate)(diphenyl(o-vinylphenyl)phosphine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PdMe(1-phenyl-3-sulfanylbut-2-en-1-onate)(diphenyl(o-vinylphenyl)phosphine)]

There total 1 articles about [PdMe(1-phenyl-3-sulfanylbut-2-en-1-onate)(diphenyl(o-vinylphenyl)phosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

3-mercapto-1-phenylbut-2-en-1-one thallium salt + [Pd(Me)(μ-I)(SMe2)]2 (101308-23-0) + o-diphenylphosphinostyrene (17165-18-3) → [PdMe(1-phenyl-3-sulfanylbut-2-en-1-onate)(diphenyl(o-vinylphenyl)phosphine)] (173986-41-9)

Guidance literature:

In acetonitrile; N2-atmosphere; addn. of stoich. amt. of Tl-salt to metal complex (0°C), stirring for 15 min, addn. of stoich. amt. of phosphine, stirring for 2 h, warming to room temp., stirring for 1 h; solvent removal (vac.), extn. into CH2Cl2, filtration, evapn., crystn. (MeOH); elem. anal.;

DOI:10.1039/DT9950004081

Reference yield:

[PdMe(1-phenyl-3-sulfanylbut-2-en-1-onate)(diphenyl(o-vinylphenyl)phosphine)] (173986-41-9) → [Pd(1-phenyl-3-sulfanylbut-2-en-1-onate)(PPh2C6H4(CHCH2CH3-o))] (174172-91-9)

Guidance literature:

In benzene; N2-atmosphere; refluxing for 1-2 h; solvent removal (vac.), crystn. (C6H6/light petroleum); isomer mixt. not sepd., detd. by (1)H- and (31)P-NMR spectroscopy; elem. anal.;

DOI:10.1039/DT9950004081

upstream raw materials:

[Pd(Me)(μ-I)(SMe2)]2

o-diphenylphosphinostyrene

Downstream raw materials:

[Pd(1-phenyl-3-sulfanylbut-2-en-1-onate)(PPh₂C₆H₄(CHCH₂CH₃-o))]