Mn(1,4-benzenedicarboxylate)(1,10-phenantroline)

Base Information

• Chemical Name: Mn(1,4-benzenedicarboxylate)(1,10-phenantroline)
• CAS No.: 375364-99-1
• Molecular Formula: C₈H₄O₄*C₁₂H₈N₂*Mn
• Molecular Weight: 399.264
• Mol file: 375364-99-1.mol

Synonyms:

Chemical Property of Mn(1,4-benzenedicarboxylate)(1,10-phenantroline)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mn(1,4-benzenedicarboxylate)(1,10-phenantroline)

There total 4 articles about Mn(1,4-benzenedicarboxylate)(1,10-phenantroline) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

1,10-Phenanthroline (66-71-7) + terephthalic acid (100-21-0) + manganese(ll) chloride (7773-01-5) → Mn(1,4-benzenedicarboxylate)(1,10-phenantroline) (375364-99-1)

Guidance literature:

In water; N,N-dimethyl-formamide; High Pressure; addn. of aq. soln. of manganese compd. to soln. of terephthalic acid andphenanthroline in DMF, stirring for 2 h at room temp., heating at 423.1 5 K for 3 d; cooling to room temp., isolation of crystals, elem. anal.;

DOI:10.1016/j.poly.2008.04.029

Reference yield: 67.9%

1,10-Phenanthroline (66-71-7) + manganese(II) chloride tetrahydrate + terephthalic acid (100-21-0) → Mn(1,4-benzenedicarboxylate)(1,10-phenantroline) (375364-99-1)

Guidance literature:

In ethanol; water; High Pressure; aq. soln. of Mn-salt added to soln. of terephthalic acid in EtOH, phenanthroline added, mixt. heated at 170°C in sealed Teflon-lined stainless vessel for 5 d, cooled to room temp.; elem. anal.;

DOI:10.1016/j.ica.2008.07.010

Reference yield: 57.0%

terephthalonitrile (623-26-7) + 1,10-Phenanthroline (66-71-7) + manganese(II) chloride tetrahydrate → Mn(1,4-benzenedicarboxylate)(1,10-phenantroline) (375364-99-1)

Guidance literature:

In water; High Pressure; hydrothermal react.; mixt. of MnCl2*4H2O, 1,4-dicyanobenzene, 1,10-phenanthroline and H2O (molar ratio 1:1:1:1777) sealed in stainless steel reactor; heated at 170°C for 72 h; cooled; crystals collected by filtration; elem. anal.;

DOI:10.1039/b102888j

upstream raw materials:

terephthalonitrile

1,10-Phenanthroline

terephthalic acid

manganese(ll) chloride