α-carboxy-4-nitrobenzyl phosphate

Base Information

• Chemical Name: α-carboxy-4-nitrobenzyl phosphate
• CAS No.: 1254332-49-4
• Molecular Formula: C₈H₅NO₈P
• Molecular Weight: 274.103
• Mol file: 1254332-49-4.mol

Synonyms:

Chemical Property of α-carboxy-4-nitrobenzyl phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of α-carboxy-4-nitrobenzyl phosphate

There total 1 articles about α-carboxy-4-nitrobenzyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C10H10NO8P(2-) (1254332-51-8) → α-carboxy-4-nitrobenzyl phosphate (1254332-49-4)

Guidance literature:

With water; potassium hydroxide; at 20 ℃; pH=13;

DOI:10.1111/j.1751-1097.2009.00576.x

Reference yield: 5.0%

α-carboxy-4-nitrobenzyl phosphate (1254332-49-4) → p-Nitrobenzyl phosphate dianion

Guidance literature:

With triethylamine carbonate; at 30 ℃; under 1 Torr;

DOI:10.1111/j.1751-1097.2009.00576.x

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + α-carboxy-4-nitrobenzyl phosphate (1254332-49-4) → α-carboxy-4-nitrobenzyl methyl phosphate (1254332-50-7)

Guidance literature:

diazomethane; α-carboxy-4-nitrobenzyl phosphate; With hydrogenchloride; In diethyl ether; water; pH=4.5; Cooling with ice;

With water; potassium hydroxide; at 20 ℃; pH=13;

DOI:10.1111/j.1751-1097.2009.00576.x

upstream raw materials:

C₁₀H₁₀NO₈P^(2-)

Downstream raw materials:

α-carboxy-4-nitrobenzyl methyl phosphate

4-nitroso-benzaldehyde

Refernces