(p-R)-(-)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene

Base Information

Chemical Name:(p-R)-(-)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene
CAS No.:1164253-20-6
Molecular Formula:C₂₇H₂₈FeO₂Si
Molecular Weight:468.451
Hs Code.:

Synonyms:

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Chemical Property of (p-R)-(-)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene

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Technology Process of (p-R)-(-)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene

There total 3 articles about (p-R)-(-)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.7%

: (S,S,p-S)-(-)-1-(tert-butyldiphenylsiloxy)-2-(4-methoxymethyl-1,3-dioxan-2-yl)ferrocene

: 7732-18-5
water

: 1167459-06-4,1095282-33-9,1164253-20-6
(p-S)-(+)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene

Guidance literature:: With catalyst: p-toluene sulfonic acid; In dichloromethane; water; refluxed for 3 h; sepd., the org. phase dried (MgSO4), filtered, solvent-removed, filteredon silica (cyclohexane/EtOAc), dissolved in pentane, stored at 4.degree .C overnight, supernatant-removed, recrystd. twice from pentane at -30°C; >99.5% ee; elem. anal.;
DOI:10.1039/b822735g

Reference yield: 77.6%

: 1164253-07-9
(rac)-1-(tert-butyldiphenylsiloxy)-2-(1,3-dioxan-2-yl)ferrocene

: 7732-18-5
water

: 1164253-20-6,1095282-33-9,1167459-06-4
(rac)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene

Guidance literature:: With catalyst: p-toluene sulfonic acid; In dichloromethane; water; refluxed for 3 h; sepd., the org. phase dried (MgSO4), filtered, solvent-removed, filteredover silica (cyclohexane/EtOAc), dissolved in pentane, stored at 4.degr ee.C overnight, supernatant-removed, dried (vac.); elem. anal.;
DOI:10.1039/b822735g

Reference yield: 70.8%

: (S,S,p-R)-(+)-1-(tert-butyldiphenylsiloxy)-2-(4-methoxymethyl-1,3-dioxan-2-yl)ferrocene

: 7732-18-5
water

: 1095282-33-9,1167459-06-4,1164253-20-6
(p-R)-(-)-1-(tert-butyldiphenylsiloxy)-2-formylferrocene

Guidance literature:: With catalyst: p-toluene sulfonic acid; In dichloromethane; water; refluxed for 3 h; sepd., the org. phase dried (MgSO4), filtered, solvent-removed, filteredon silica (cyclohexane/EtOAc), dissolved in pentane, stored at -30.degr ee.C overnight, supernatant-removed, recrystd. twice from pentane at -30°C; >99.5% ee; elem. anal.;
DOI:10.1039/b822735g