carbonylchloro[diphenyl(2-methylthioethyl)phosphine]rhodium(I)

Base Information

• Chemical Name: carbonylchloro[diphenyl(2-methylthioethyl)phosphine]rhodium(I)
• CAS No.: 114630-33-0
• Molecular Formula: C₁₆H₁₇ClOPRhS
• Molecular Weight: 426.709
• Mol file: 114630-33-0.mol

Synonyms:

Chemical Property of carbonylchloro[diphenyl(2-methylthioethyl)phosphine]rhodium(I)

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of carbonylchloro[diphenyl(2-methylthioethyl)phosphine]rhodium(I)

There total 1 articles about carbonylchloro[diphenyl(2-methylthioethyl)phosphine]rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

di(rhodium)tetracarbonyl dichloride + 1-(methylthio)-2-(diphenylphosphino)ethane (20859-51-2) → carbonylchloro[diphenyl(2-methylthioethyl)phosphine]rhodium(I) (114630-33-0)

Guidance literature:

In acetone; byproducts: CO; A three-necked-flask is charged with Rh2(μ-Cl)2(CO)4 and Ph2PCH2CH2SCH3. The flask is purged with Ar, then acetone is introduced. The reactants dissolved and CO is evolved.; After 15 min the solvent is removed. The residue is washed with ether and filtration gives the product. Elem. anal.;

DOI:10.1016/S0022-328X(00)99464-6

upstream raw materials:

1-(methylthio)-2-(diphenylphosphino)ethane