fac-N(PPh₃)2[Fe(CO)3(SePh)3]

Base Information

• Chemical Name: fac-N(PPh₃)2[Fe(CO)3(SePh)3]
• CAS No.: 147579-43-9
• Molecular Formula: C₂₁H₁₅FeO₃Se₃*C₃₆H₃₀NP₂
• Molecular Weight: 1146.66
• Mol file: 147579-43-9.mol

Synonyms:

Chemical Property of fac-N(PPh₃)2[Fe(CO)3(SePh)3]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of fac-N(PPh₃)2[Fe(CO)3(SePh)3]

There total 2 articles about fac-N(PPh₃)2[Fe(CO)3(SePh)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

bis(triphenylphosphine)iminium tetracarbonylhydridoferrate(0) (56791-54-9) + (P(C6H5)3)2N(1+)*C6H5SeFe(CO)4(1-) = {(P(C6H5)3)2N}{C6H5SeFe(CO)4} (147579-46-2) → fac-N(PPh3)2[Fe(CO)3(SePh)3] (147579-43-9,151379-47-4)

Guidance literature:

In tetrahydrofuran; (N2), 2 equivalents of (PhSe)2 in THF added to a stirred soln. of the Fe-complex at ambient temp., stirred at room temp. for 40 h; solvent removed under vacuum, hexane added, pptd. from THF/hexane, elem. anal.;

Reference yield: 92.0%

bis(triphenylphosphine)iminium tetracarbonylhydridoferrate(0) (56791-54-9) + diphenyl diselenide (1666-13-3) → fac-N(PPh3)2[Fe(CO)3(SePh)3] (147579-43-9,151379-47-4)

Guidance literature:

In tetrahydrofuran; (N2), 2 equivalents of (PhSe)2 in THF added to a stirred soln. of the Fe-complex at ambient temp., stirred at room temp. for 40 h; solvent removed under vacuum, hexane added, pptd. from THF/hexane, elem. anal.;

Reference yield: 91.0%

1,10-Phenanthroline (66-71-7) + iron(II) perchlorate hexahydrate + fac-N(PPh3)2[Fe(CO)3(SePh)3] (147579-43-9,151379-47-4) → [Fe(CO)2(SeC6H5)2(C12H8N2)] (203922-65-0)

Guidance literature:

In acetonitrile; byproducts: (N(PPh3)2)ClO4; (N2); stirring (room temp., overnight); solvent removal (reduced pressure), dissoln. (THF, under N2), filtration, refrigerator (-15°C, 3 weeks); elem. anal.;

DOI:10.1039/a705247b

upstream raw materials:

bis(triphenylphosphine)iminium tetracarbonylhydridoferrate⁽⁰⁾

diphenyl diselenide

(P(C₆H₅)3)2N⁽¹⁺⁾*C₆H₅SeFe(CO)4^(1-) = {(P(C₆H₅)3)2N}{C₆H₅SeFe(CO)4}

Downstream raw materials:

[Fe(CO)2(SeC₆H₅)2(C₁₂H₈N₂)]

(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(SeC₆H₅)2Fe(NO)2^(1-)=[(C₆H₅)3PNP(C₆H₅)3][(SeC₆H₅)2Fe(NO)2]

(C₅H₅)Fe(CO)2(SeC₆H₅)

[[(C₆H₅)3P]2N]⁽¹⁺⁾*[Ni(CO)(SeC₆H₅)3]^(1-)=[[(C₆H₅)3P]2N][Ni(CO)(SeC₆H₅)3]