(CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂)

Base Information

Chemical Name:(CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂)
CAS No.:101471-46-9
Molecular Formula:C₃₅H₃₃FeIrO₃P₂
Molecular Weight:811.66
Hs Code.:

(CO)3Fe(P(C<sub>6</sub>H<sub>5</sub>)2)2Ir(H)(C<sub>8</sub>H<sub>12</sub>)

Synonyms:

Suppliers and Price of (CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂)

There total 1 articles about (CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: chloro(1,5-cyclooctadiene)iridium(I) dimer

: 18399-67-2,40697-11-8
trans-Fe(CO)3(PPh₂H)2

: 101471-47-0
(CO)3Fe(P(C₆H₅)2)2Ir(Cl)(C₈H₁₂)

: 101471-46-9
(CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂)

Guidance literature:: With n-butyllithium; acetic acid; In tetrahydrofuran; hexane; 2 equiv of n-BuLi in THF was added under N2 to a THF soln. of Fe-complex, mixt. was stirred for 5 min, this soln. was added via cannula to a THF soln. of Ir-complex, mixt. was stirred for 5 min, glacial AcOH was added, soln. was stirred for 10 min; soln. was evapd., residue was supported onto SiO2 by evapn. of a CH2Cl2 soln., this SiO2 was loaded at a SiO2 column, eluted with CH2Cl2-hexane, eluate was evapd.; hydrido complex was not isolated in pure form, characterized spect.;
DOI:10.1021/om00137a001

Reference yield: 24.0%

: 101471-46-9
(CO)3Fe(P(C₆H₅)2)2Ir(H)(C₈H₁₂)

: 101471-47-0
(CO)3Fe(P(C₆H₅)2)2Ir(Cl)(C₈H₁₂)

: 101471-48-1
(CO)3Fe(P(C₆H₅)2)2Ir(H)(CO)(P(C₆H₅)3)

Guidance literature:: With carbon monoxide; triphenylphosphine; In toluene; a Fischer-Porter pressure bottle was charged with COD-complex, PPh3, and toluene and pressurized to 80 psi with CO, mixt. was stirred for 23 h at 22°C; vented to atmosphere, soln. was evapd., residue was chromd.on a SiO2 column (eluent CH2Cl2-hexane);
DOI:10.1021/om00137a001