O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate

Base Information

• Chemical Name: O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate
• CAS No.: 1000387-38-1
• Molecular Formula: C₄₁H₃₅O₁₁PS
• Molecular Weight: 766.762
• Mol file: 1000387-38-1.mol

Synonyms:

Chemical Property of O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate

There total 2 articles about O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl thiocyanate → O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate (1000387-38-1)

Guidance literature:

With dimethylphenylphosphonite; at 50 ℃; for 1h;

DOI:10.1016/j.carres.2007.12.009

Reference yield: 41.0%

phenylphosphonous acid dimethyl ester (2946-61-4) + 2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl thiocyanate → O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate (1000387-38-1)

Guidance literature:

at 50 ℃; for 1h;

DOI:10.1016/j.tetlet.2007.09.162

Reference yield: 69.0%

O-methyl-S-(2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl) phenylthiophosphonate (1000387-38-1) + benzyl alcohol (100-51-6,185532-71-2) → benzyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranoside

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate;

DOI:10.1016/j.tetlet.2007.09.162

upstream raw materials:

phenylphosphonous acid dimethyl ester