[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]BF₄

Base Information

• Chemical Name: [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]BF₄
• CAS No.: 329984-39-6
• Molecular Formula: BF₄*C₄₁H₅₄NO₂PRe
• Molecular Weight: 896.871

Synonyms:

Chemical Property of [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]BF₄

Chemical Property:

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Useful:

Technology Process of [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]BF₄

There total 1 articles about [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

{(C5Me5)Re(CO)2(NO)}BF4 + Tris(4-tert-butylphenyl)phosphan (54409-77-7) → [(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CO)](1+)*BF4(1-)=[(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CO)]BF4 (329984-39-6)

Guidance literature:

With PhIO; In acetonitrile; butanone; CH3CN and Re complex in Schlenk flask cooled to 0°C; PhIO added with stirring; soln. was kept at room temp. for 3 h; solvent removed; residue washed (Et2O); P(C6H4-t-C4H9)3 and 2-butanone added; mixt. refluxedfor 3 h; solvent removed by rotary evapn.; residue transferred to fritted glass funnel; washed (hexane, Et2O); dissolved in acetone; soln. was layered with Et2O; stored at -20°C for 2 d; filtered; washed (Et2O); air dried; elem. anal.;

DOI:10.1016/S0022-328X(00)00528-3

Reference yield: 53.0%

[(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CO)](1+)*BF4(1-)=[(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CO)]BF4 (329984-39-6) + borane tetrahydrofuran + lithium triethylborohydride (22560-16-3) → [(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CH3)] (329984-47-6)

Guidance literature:

In tetrahydrofuran; soln. of LiEt3BH in THF added to stirred suspn. of Re complex in THF in Schlenk flask; after 10 min BH3*THF added; after 0.5 h solvent removed in vac.; extd. (benzene); passed through column of SiO2; solvent removed by rotary evapn. and oil pump vac.; elem. anal.;

DOI:10.1016/S0022-328X(00)00528-3

upstream raw materials:

Tris(4-tert-butylphenyl)phosphan

Downstream raw materials:

[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]

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