CpFe(CO)2SSiPh₃

Base Information

• Chemical Name: CpFe(CO)2SSiPh₃
• CAS No.: 531509-77-0
• Molecular Formula: C₂₅H₂₀FeO₂SSi
• Molecular Weight: 468.431
• Mol file: 531509-77-0.mol

Synonyms:

Chemical Property of CpFe(CO)2SSiPh₃

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of CpFe(CO)2SSiPh₃

There total 1 articles about CpFe(CO)2SSiPh₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate + LiSSiPh3*Et2O → CpFe(CO)2SSiPh3 (531509-77-0)

Guidance literature:

In dichloromethane; under inert atm. LiSSiPh3*Et2O was added to soln. (CpFe(CO)2(THF)2)BF4 in CH2Cl2 at room temp. and stirred for 1 h; soln. was filtered and evapd. to dryness, residue was dissolved in CH2Cl2, layered with hexane and kept at -30°C; elem. anal.;

DOI:10.1021/ic030049g

Reference yield:

CpFe(CO)2SSiPh3 (531509-77-0) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → CpFe(CO)2SS(O)OSiPh3 (531509-78-1)

Guidance literature:

In benzene-d6; SO2 was injected into soln. Fe complex in C6D6, 2 h;

DOI:10.1021/ic030049g

Downstream raw materials:

CpFe(CO)2SS(O)OSiPh₃