(C₅(CH₃)5)Ti(CH₃)2(OSi(CH₂CH₂Si(C₆H₅)2CH₃)3)

Base Information

• Chemical Name: (C₅(CH₃)5)Ti(CH₃)2(OSi(CH₂CH₂Si(C₆H₅)2CH₃)3)
• CAS No.: 852447-88-2
• Molecular Formula: C₅₇H₇₂OSi₄Ti
• Molecular Weight: 933.42
• Mol file: 852447-88-2.mol

Synonyms:

Chemical Property of (C₅(CH₃)5)Ti(CH₃)2(OSi(CH₂CH₂Si(C₆H₅)2CH₃)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅(CH₃)5)Ti(CH₃)2(OSi(CH₂CH₂Si(C₆H₅)2CH₃)3)

There total 1 articles about (C₅(CH₃)5)Ti(CH₃)2(OSi(CH₂CH₂Si(C₆H₅)2CH₃)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

trimethyl(pentamethylcyclopentadienyl)titanium(IV) (107333-47-1) + HOSi(CH2CH2Si(C6H5)2CH3)3 (852447-83-7) → (C5(CH3)5)Ti(CH3)2(OSi(CH2CH2Si(C6H5)2CH3)3) (852447-88-2)

Guidance literature:

In toluene; byproducts: CH4; under Ar; ligand added to soln. of Ti complex in toluene; stirred at room temp. for 12 h; solvent removed at reduced pressure; extd. with pentane; filtered; solvent removed at reduced pressure; elem. anal.;

DOI:10.1021/om049010p

Reference yield: 90.0%

(C5(CH3)5)Ti(CH3)2(OSi(CH2CH2Si(C6H5)2CH3)3) (852447-88-2) + tris(pentafluorophenyl)borate (1109-15-5) → (C5(CH3)5)Ti(C6F5)(CH3)(OSi(CH2CH2Si(C6H5)2CH3)3) (852447-91-7)

Guidance literature:

In toluene; under Ar; Ti complex and B(C6F5)3 (molar ratio 2:1) dissolved in tolueneat room temp.; stirred for several d; volatiles removed under high vac. at 45°C; elem. anal.;

DOI:10.1021/om049010p

Reference yield:

(C5(CH3)5)Ti(CH3)2(OSi(CH2CH2Si(C6H5)2CH3)3) (852447-88-2) + tris(pentafluorophenyl)borate (1109-15-5) → (C5(CH3)5)Ti(CH3)(CH3B(C6F5)3)(OSi(CH2CH2Si(C6H5)2CH3)3)

Guidance literature:

In benzene-d6; under Ar; in NMR tube; Ti complex and B(C6F5)3 (molar ratio 1:1) dissolved in benzene-d6 at room temp.; shaken; not isolated; monitored by (1)H NMR spectra;

DOI:10.1021/om049010p

upstream raw materials:

trimethyl(pentamethylcyclopentadienyl)titanium(IV)

HOSi(CH₂CH₂Si(C₆H₅)2CH₃)3

Downstream raw materials:

dimethylpentafluorophenylborane

(C₅(CH₃)5)Ti(C₆F₅)(CH₃)(OSi(CH₂CH₂Si(C₆H₅)2CH₃)3)

(C₅(CH₃)5)Ti(C₆F₅)(CH₂B(C₆F₅)2)(OSi(CH₂CH₂Si(C₆H₅)2CH₃)3)

methylbis(pentafluorophenyl)borane