2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide

Base Information

• Chemical Name: 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide
• CAS No.: 1064078-46-1
• Molecular Formula: C₂₅H₂₅N
• Molecular Weight: 339.48
• Mol file: 1064078-46-1.mol

Synonyms:

Chemical Property of 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide

There total 1 articles about 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C100H100FeN6 → 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide (1064078-46-1) + C50H50Fe2N2 + C25H25N

Guidance literature:

In diethyl ether; for 2.5h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.inorgchem.5b00730

Reference yield: 98.0%

2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide (1064078-46-1) + cobalt(II) iodide → [cobalt(II)(iodide)2(C6H2(2,4,6-Me3C6H3)2isocyanide)3] (1262953-76-3)

Guidance literature:

In tetrahydrofuran; Schlenk or glove box techniques, under N2; suspn. of CoI2 and CNC6H2(C6H3(CH3)3)2 (3 equiv.) stirred at room temp. for 1 h; filtered, volatiles removed in vac., residue stirred in Et2O and evapd. to dryness (3 times);

DOI:10.1016/j.ica.2010.08.024

Reference yield: 94.6%

carbonyl(η-5-cyclopentadienyl)diiodocobalt(III) + 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide (1064078-46-1) → C30H30CoI2N

Guidance literature:

In benzene; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/acs.organomet.7b00164

Downstream raw materials:

Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)⁽¹⁺⁾*CF₃SO₃^(1-)=Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)CF₃SO₃

(Cu(((CH₃)3C₆H₂)2C₆H₃NC)((CH₂)4O)Br)2

Cu(((CH₃)3C₆H₂)2C₆H₃NC)2Cl

(Cu(((CH₃)3C₆H₂)2C₆H₃NC)((CH₂)4O)Cl)2