(1aS,8R,8aR,8bS)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

Base Information

Chemical Name:(1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole
CAS No.:129056-08-2
Molecular Formula:C₂₇H₃₆N₂O₆SSi
Molecular Weight:544.744
Hs Code.:

(1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

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Chemical Property of (1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

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Technology Process of (1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

There total 4 articles about (1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 129077-34-5
(1aS*,8R*,8aR*,8bS*)-4,7-dibenzyloxy-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-1-p-toluenesulfonyl-1,1a,2,8,8a,8b-hexahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

: 129056-08-2
(1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / 10percent Pd/C / ethyl acetate / 0.17 h / Ambient temperature

2: O₂ / ethyl acetate / 0.17 h / Ambient temperature

With hydrogen; oxygen; palladium on activated charcoal; In ethyl acetate;

Reference yield:

: 129077-33-4
(1aS*,8R*,9R*,9aS*)-4,7-dibenzyloxy-9-hydroxy-6-methoxy-5,8-dimethyl-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

: 129056-08-2
(1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / PCC, molecular sieves 4A / CH₂Cl₂ / 35 h / Ambient temperature

2: 100 percent / Et₃N / CH₂Cl₂ / 0.17 h / Ambient temperature

3: H₂ / 10percent Pd/C / ethyl acetate / 0.17 h / Ambient temperature

4: O₂ / ethyl acetate / 0.17 h / Ambient temperature

With 4 A molecular sieve; hydrogen; oxygen; triethylamine; pyridinium chlorochromate; palladium on activated charcoal; In dichloromethane; ethyl acetate;

Reference yield:

: 129056-07-1
(1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

: 129056-08-2
(1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / Et₃N / CH₂Cl₂ / 0.17 h / Ambient temperature

2: H₂ / 10percent Pd/C / ethyl acetate / 0.17 h / Ambient temperature

3: O₂ / ethyl acetate / 0.17 h / Ambient temperature

With hydrogen; oxygen; triethylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate;