(cyclopentadienylbis(tetasulfido)molybdenum)tetraphenylphosphonium salt

Base Information

• Chemical Name: (cyclopentadienylbis(tetasulfido)molybdenum)tetraphenylphosphonium salt
• CAS No.: 122116-28-3
• Molecular Formula: C₅H₅MoS₈*C₂₄H₂₀P
• Molecular Weight: 756.959
• Mol file: 122116-28-3.mol

Synonyms:

Chemical Property of (cyclopentadienylbis(tetasulfido)molybdenum)tetraphenylphosphonium salt

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of (cyclopentadienylbis(tetasulfido)molybdenum)tetraphenylphosphonium salt

There total 2 articles about (cyclopentadienylbis(tetasulfido)molybdenum)tetraphenylphosphonium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

sulfur (10544-50-0) + dipotassium trisulfide (37488-75-8) + cyclopentadienylmolybdenum tricarbonyl dimer + tetraphenylphosphonium bromide (2751-90-8) → (cyclopentadienylbis(tetasulfido)molybdenum)tetraphenylphosphonium salt (122116-28-3)

Guidance literature:

In N,N-dimethyl-formamide; acetonitrile; in acetonitrile/DMF (5:1), at 25°C, 3 h, addn. of elemental sulfur, stirring at 25° C, 1 h; filtration, layering with Et2O, storing at 4 °C overnight, elem. anal.;

DOI:10.1021/om00111a034

Reference yield:

sulfur (10544-50-0) + {(C5H5)Mo(CO)2(S2)}(1-)*(C6H5)4P(1+)={(C5H5)Mo(CO)2(S2)}(C6H5)4P (122116-26-1) → (cyclopentadienylbis(tetasulfido)molybdenum)tetraphenylphosphonium salt (122116-28-3)

Guidance literature:

In acetonitrile; stirring 1 h at 25 °C;

DOI:10.1021/om00111a034

upstream raw materials:

sulfur

dipotassium trisulfide

tetraphenylphosphonium bromide

{(C₅H₅)Mo(CO)2(S₂)}^(1-)*(C₆H₅)4P⁽¹⁺⁾={(C₅H₅)Mo(CO)2(S₂)}(C₆H₅)4P