thallium tris(4,4-dimethyl-2-oxazolinyl)phenylborate

Base Information

Chemical Name:thallium tris(4,4-dimethyl-2-oxazolinyl)phenylborate
CAS No.:1228657-54-2
Molecular Formula:C₂₁H₂₉BN₃O₃*Tl
Molecular Weight:586.674
Hs Code.:

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Chemical Property of thallium tris(4,4-dimethyl-2-oxazolinyl)phenylborate

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Technology Process of thallium tris(4,4-dimethyl-2-oxazolinyl)phenylborate

There total 1 articles about thallium tris(4,4-dimethyl-2-oxazolinyl)phenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: thallium(I) nitrate

: 1030839-74-7
lithium tris(4,4-dimethyl-2-oxazolinyl)phenylborate

: 1228657-54-2
thallium(I) tris(4,4-dimethyl-2-oxazolinyl)phenylborate

Guidance literature:: In tetrahydrofuran; dichloromethane; water; using Schlenk techniques; dissolving of TlNO3 in H2O/CH2Cl2 (1:1), dissolving of Li(PhB(C3H2NOMe2)3) in min. amt. of THF, addn. to soln. TlNO3, pptn., vigorous stirring for 30 min; sepn. of liquid, decanting of aq. layer, washing of org. layer with H2O,evapn. of volatiles from org. layer under reduced pressure, truturation with pentane, pptn., recrystn. from toluene at -35°C; elem. anal .;
DOI:10.1021/om100515u

Reference yield: 93.2%

: 1228657-54-2
thallium(I) tris(4,4-dimethyl-2-oxazolinyl)phenylborate

: 7789-46-0
iron(II) bromide

: (tris(4,4-dimethyl-2-oxazolinyl)phenylborate)₂Fe

Guidance literature:: In tetrahydrofuran; at 20 ℃; Inert atmosphere;
DOI:10.1021/acs.inorgchem.9b00359

Reference yield: 92.0%

: di(rhodium)tetracarbonyl dichloride

: 1228657-54-2
thallium(I) tris(4,4-dimethyl-2-oxazolinyl)phenylborate

: tris(4,4-dimethyl-2-oxazolinyl)phenylborato rhodium(I) dicarbonyl

Guidance literature:: In benzene; byproducts: TlCl; using Schlenk techniques; addn. of benzene to mixt. of Tl(PhB(C3H2NOMe2)3) and (Rh(CO)2(μ-Cl))2 (0.5 equiv.), stirring for 24 h at room temp.; filtration, evapn. under vac., dissolving in Et2O, stirring for 2 h, filtration, evapn. to dryness; as mixt. of isomers; elem. anal.;
DOI:10.1021/om100515u