C₆₀H₉₂N₃O₂₂PS₂

Base Information

• Chemical Name: C₆₀H₉₂N₃O₂₂PS₂
• CAS No.: 1310568-67-2
• Molecular Formula: C₆₀H₉₂N₃O₂₂PS₂
• Molecular Weight: 1302.5
• Mol file: 1310568-67-2.mol

Synonyms:

Chemical Property of C₆₀H₉₂N₃O₂₂PS₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₀H₉₂N₃O₂₂PS₂

There total 15 articles about C₆₀H₉₂N₃O₂₂PS₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C28H47BrO11 (1310568-59-2) → C60H92N3O22PS2 (1310568-67-2)

Guidance literature:

Multi-step reaction with 6 steps

1: 2 h / 160 °C

2: sodium tetrahydroborate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran; N,N-dimethyl-formamide / 2 h / 20 °C

3: potassium carbonate; potassium iodide / acetone / 48 h / 60 °C

4: trifluoroacetic acid / dichloromethane / 0 - 20 °C

5: dmap; triethylamine / dichloromethane; N,N-dimethyl-formamide / 0 - 20 °C / Inert atmosphere

6: trimethylsilyl bromide / dichloromethane / 20 °C

With dmap; sodium tetrahydroborate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; trimethylsilyl bromide; potassium carbonate; triethylamine; trifluoroacetic acid; potassium iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetone; 3: Williamson reaction;

DOI:10.1016/j.tetlet.2011.03.144

Reference yield:

C28H48O12 (1310568-58-1) → C60H92N3O22PS2 (1310568-67-2)

Guidance literature:

Multi-step reaction with 7 steps

1: phosphorus tribromide / dichloromethane / 2 h / 0 - 20 °C

2: 2 h / 160 °C

3: sodium tetrahydroborate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran; N,N-dimethyl-formamide / 2 h / 20 °C

4: potassium carbonate; potassium iodide / acetone / 48 h / 60 °C

5: trifluoroacetic acid / dichloromethane / 0 - 20 °C

6: dmap; triethylamine / dichloromethane; N,N-dimethyl-formamide / 0 - 20 °C / Inert atmosphere

7: trimethylsilyl bromide / dichloromethane / 20 °C

With dmap; sodium tetrahydroborate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; trimethylsilyl bromide; phosphorus tribromide; potassium carbonate; triethylamine; trifluoroacetic acid; potassium iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetone; 4: Williamson reaction;

DOI:10.1016/j.tetlet.2011.03.144

Reference yield:

C29H53O14P (1310568-61-6) → C60H92N3O22PS2 (1310568-67-2)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium carbonate; potassium iodide / acetone / 48 h / 60 °C

2: trifluoroacetic acid / dichloromethane / 0 - 20 °C

3: dmap; triethylamine / dichloromethane; N,N-dimethyl-formamide / 0 - 20 °C / Inert atmosphere

4: trimethylsilyl bromide / dichloromethane / 20 °C

With dmap; trimethylsilyl bromide; potassium carbonate; triethylamine; trifluoroacetic acid; potassium iodide; In dichloromethane; N,N-dimethyl-formamide; acetone; 1: Williamson reaction;

DOI:10.1016/j.tetlet.2011.03.144

upstream raw materials:

C₃₇H₇₀NO₁₇P

2-(2-(2-(2-((tert-butoxycarbonyl)amino)ethoxy)ethoxy)ethoxy)ethyl-(4'-methylbenzolsulfonate)

C₂₈H₄₈O₁₂

C₂₈H₄₇BrO₁₁

Refernces