Technology Process of 2,8-difluoro-5,11-bis(4-fluorophenyl)-6,12-dithien-2-yltetracene
There total 3 articles about 2,8-difluoro-5,11-bis(4-fluorophenyl)-6,12-dithien-2-yltetracene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
collidine;
In
5,5-dimethyl-1,3-cyclohexadiene;
at 80 - 95 ℃;
for 7h;
Inert atmosphere;
DOI:10.1002/ejoc.201100033
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: magnesium; isopropyl bromide / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere
1.2: 0 °C / Inert atmosphere; Reflux
2.1: methanesulfonyl chloride; triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere
3.1: collidine / 5,5-dimethyl-1,3-cyclohexadiene / 7 h / 80 - 95 °C / Inert atmosphere
With
magnesium; methanesulfonyl chloride; triethylamine; isopropyl bromide;
In
tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane;
1.1: Grignard reaction / 1.2: Grignard reaction;
DOI:10.1002/ejoc.201100033
- Guidance literature:
-
Multi-step reaction with 2 steps
1: methanesulfonyl chloride; triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere
2: collidine / 5,5-dimethyl-1,3-cyclohexadiene / 7 h / 80 - 95 °C / Inert atmosphere
With
methanesulfonyl chloride; triethylamine;
In
5,5-dimethyl-1,3-cyclohexadiene; dichloromethane;
DOI:10.1002/ejoc.201100033
