(3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)

Base Information

Chemical Name:(3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)
CAS No.:125291-11-4
Molecular Formula:C₅₂H₅₇O₁₄P₃
Molecular Weight:998.937
Hs Code.:

(3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo<d>-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)

Synonyms:

Suppliers and Price of (3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)

There total 4 articles about (3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 125291-09-0,130697-85-7
(3aα,4β,5α,6β,7α,7aα)-6,7-bis(benzyloxy)hexahydro-2,2,5-trimethylbenzo-1,3(2H)-dioxol-4-ol

: 125291-11-4,130697-87-9
(3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / 10percent Pd-C / ethanol / 16 h

2: nBuLi, iPr₂NH / tetrahydrofuran

With n-butyllithium; hydrogen; diisopropylamine; palladium on activated charcoal; In tetrahydrofuran; ethanol;
DOI:10.1016/S0040-4039(00)99439-5

Reference yield:

: 118993-51-4,130633-17-9,130697-67-5,131435-02-4
(3aα,4α,5β,6β,7β,7aα)-4,5-bis(benzyloxy)-6,7-epoxyhexahydro-2,2-dimethylbenzo-1,3-dioxole

: 125291-11-4,130697-87-9
(3aα,4α,5β,6α,7β,7aα)-hexahydro-2,2,6-trimethylbenzo-1,3(2H)-dioxol-4,5,7-triol tris(dibenzylphosphate)

Guidance literature:: Multi-step reaction with 3 steps

1: 71 percent / CuCN / diethyl ether; tetrahydrofuran / 22 h / -30 °C

2: 97 percent / H₂ / 10percent Pd-C / ethanol / 16 h / Ambient temperature

3: 1.) n-BuLi, diisopropylamine / 1.) hexanes, THF, -30 - -25 deg C, 15 min 2.) 0 deg C, 3h

With n-butyllithium; hydrogen; diisopropylamine; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol;