{1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)

Base Information

• Chemical Name: {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)
• CAS No.: 168609-59-4
• Molecular Formula: C₁₄H₁₄BrIPtS₂
• Molecular Weight: 648.286
• Mol file: 168609-59-4.mol

Synonyms:

Chemical Property of {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)

There total 4 articles about {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

{1,2-bis(phenylthio)ethane}dibromoplatinum(II) (104975-53-3,105017-35-4,71513-67-2) + tetraethylammonium iodide (68-05-3) → {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II) (168609-59-4,153660-78-7)

Guidance literature:

With silver nitrate; In N,N-dimethyl-formamide; byproducts: AgBr; addn. of AgNO3 to a soln. of the Pt complex in DMF (60°C), stirring the mixt. in the dark for 30 min, AgCl filtered off, addn. of NEt4I, stirring at 80°C, 10 min; crystn. on slowly cooling to room temp. and addn. of hot water to the DMF soln., filtration, washing (cold methanol, twice diethyl ether), drying under reduced pressure, elem. anal.;

DOI:10.1039/DT9940000169

Reference yield:

{1,2-bis(phenylthio)ethane}chloroiodoplatinum(II) (153660-77-6,168609-58-3) + bromide (10097-32-2,16759-25-4,24959-67-9) → {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II) (168609-59-4,153660-78-7) + chloride (16887-00-6)

Guidance literature:

In methanol; addn. of the Pt complex in DMF to a methanolic soln. of the nucleophile previously brought to 25°C in a thermostated cell in the spectrophotometer, constant ionic strength: 0.5 mol/dm**3 LiClO4, back react. on addn. of Cl(1-); not isolated, detn. by spectrophotometry (280-400 nm); Kinetics;

DOI:10.1039/DT9940000169

Reference yield:

{1,2-bis(phenylthio)ethane}dibromoplatinum(II) (104975-53-3,105017-35-4,71513-67-2) + iodide (14362-44-8,20461-54-5,69239-56-1) → {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II) (168609-59-4,153660-78-7) + bromide (10097-32-2,16759-25-4,24959-67-9)

Guidance literature:

In methanol; addn. of the Pt complex in DMF to a methanolic soln. of the nucleophile previously brought to 25°C in a thermostated cell in the spectrophotometer, constant ionic strength: 0.5 mol/dm**3 LiClO4, back react. on addn. of Br(1-); not isolated, detn. by spectrophotometry (280-400 nm); Kinetics;

DOI:10.1039/DT9940000169

upstream raw materials:

{1,2-bis(phenylthio)ethane}dibromoplatinum(II)

tetraethylammonium iodide

{1,2-bis(phenylthio)ethane}diiodoplatinum(II)

bromide

Refernces