spinosyn D aglycone

Base Information

Chemical Name:spinosyn D aglycone
CAS No.:149439-79-2
Molecular Formula:C₂₅H₃₆O₅
Molecular Weight:416.558
Hs Code.:

Synonyms:

Suppliers and Price of spinosyn D aglycone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Cayman Chemical
Spinosyn D aglycone
2.5mg
$ 926.00

Cayman Chemical
Spinosyn D aglycone
500μg
$ 285.00

Total 5 raw suppliers

Chemical Property of spinosyn D aglycone

Chemical Property:

Boiling Point:641.9±55.0 °C(Predicted)
PKA:14.28±0.70(Predicted)
Density:1.19±0.1 g/cm3(Predicted)

Purity/Quality:

>95% by HPLC ^*data from raw suppliers

Spinosyn D aglycone ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses Spinosyn D aglycone is an acid degradation product produced by hydrolysis of both saccharide groups on spinosyn D, the minor component of the commercial insecticide, Spinosad. Spinosyn D aglycone is only weakly active as an insecticide as the saccharides are considered essential for potent activity. Despite the importance of spinosyns as agro-chemical insecticides and more recently as animal health products, there are few published reports of the biological activity or the levels of spinosyn D aglycone in animals or in the environment.

Technology Process of spinosyn D aglycone

There total 3 articles about spinosyn D aglycone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 9-pseudoaglycone of spinosyn D

: 149439-79-2
spinosyn D aglycone

Guidance literature:: With sulfuric acid; In water; at 80 ℃; for 3.75h; pH=1.7;
DOI:10.7164/antibiotics.51.795

Reference yield:

: 149439-72-5
3'-des-O-methyl-3'-keto spinosyn D

: 149439-79-2
spinosyn D aglycone

Guidance literature:: Multi-step reaction with 2 steps

1: 42 percent / K₂CO₃ / methanol / 1 h / 20 °C

2: 63 percent / 1 N H₂SO₄ / H₂O / 3.75 h / 80 °C / pH 1.7

With sulfuric acid; potassium carbonate; In methanol; water; 1: Elimination / 2: Hydrolysis;
DOI:10.7164/antibiotics.51.795

Reference yield:

: spinosyn J of D

: 149439-79-2
spinosyn D aglycone

Guidance literature:: Multi-step reaction with 3 steps

1: N-chlorosuccinimide; diisopropyl sulfide / CH₂Cl₂ / 6.25 h / -78 °C

2: 42 percent / K₂CO₃ / methanol / 1 h / 20 °C

3: 63 percent / 1 N H₂SO₄ / H₂O / 3.75 h / 80 °C / pH 1.7

With N-chloro-succinimide; diisopropylsulfide; sulfuric acid; potassium carbonate; In methanol; dichloromethane; water; 1: Oxidation / 2: Elimination / 3: Hydrolysis;
DOI:10.7164/antibiotics.51.795