Stannylene, [2,6-bis[(dimethylamino)methyl]phenyl](4-methylphenyl)-

Base Information

• Chemical Name: Stannylene, [2,6-bis[(dimethylamino)methyl]phenyl](4-methylphenyl)-
• CAS No.: 138174-70-6
• Molecular Formula: C19H26N2Sn
• Molecular Weight: 401.139
• Mol file: 138174-70-6.mol

Synonyms:

Chemical Property of Stannylene, [2,6-bis[(dimethylamino)methyl]phenyl](4-methylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Stannylene, [2,6-bis[(dimethylamino)methyl]phenyl](4-methylphenyl)-

There total 2 articles about Stannylene, [2,6-bis[(dimethylamino)methyl]phenyl](4-methylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(2,6-bis-{(dimethylamino)methyl}phenyl)tin chloride (138174-69-3) + p-tolyllithium (2417-95-0) → (2,6-bis-{(dimethylamino)methyl}phenyl)4-tolyltin (II) (138174-70-6)

Guidance literature:

In not given; recrystn. (pentane); elem. anal.;

DOI:10.1021/om00107a038

Reference yield:

2,6-bis(dimethylaminomethyl)phenyllithium (313963-74-5) → (2,6-bis-{(dimethylamino)methyl}phenyl)4-tolyltin (II) (138174-70-6)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran; diethyl ether

2: not given

In tetrahydrofuran; diethyl ether;

DOI:10.1021/om00107a038

Reference yield: 80.0%

(2,6-bis-{(dimethylamino)methyl}phenyl)4-tolyltin (II) (138174-70-6) → trans-(2,6-bis-{(dimethylamino)methyl}phenyl)4-tolyltin(IV) diiodide (138174-87-5)

Guidance literature:

With iodine; In benzene; (N2); molar ratio; addn. during 15 min; concd. in vacuo; washed (pentane); dried in vacuo; elem. anal.;

DOI:10.1016/0022-328X(91)86308-D

upstream raw materials:

(2,6-bis-{(dimethylamino)methyl}phenyl)tin chloride

p-tolyllithium

2,6-bis(dimethylaminomethyl)phenyllithium

Downstream raw materials:

trans-(2,6-bis-{(dimethylamino)methyl}phenyl)4-tolyltin(IV) diiodide