C₅₁H₆₁NO₁₃

Base Information

• Chemical Name: C₅₁H₆₁NO₁₃
• CAS No.: 318954-61-9
• Molecular Formula: C₅₁H₆₁NO₁₃
• Molecular Weight: 896.044
• Mol file: 318954-61-9.mol

Synonyms:

Chemical Property of C₅₁H₆₁NO₁₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₁H₆₁NO₁₃

There total 9 articles about C₅₁H₆₁NO₁₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzaldehyde dimethyl acetal (1125-88-8) → C51H61NO13 (318954-61-9)

Guidance literature:

Multi-step reaction with 7 steps

1: 95 percent / H(+) / dimethylformamide

2: 85 percent / PFL / tetrahydrofuran / 60 °C / Enzymatic reaction

3: TFAA; DMSO; Et₃N / CH₂Cl₂

4: NH₂OH*HCl; NaOAc / ethanol / 50 °C

5: 94 percent / pyridine / 0 - 40 °C

6: PhSCl; 2,6-di-tert-butyl-4-methylpyridine; 3 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.5 h / -78 - -55 °C

7: CH₂Cl₂; diethyl ether

With pyridine; 2,6-di-tert-butyl-4-methylpyridine; 3 A molecular sieve; hydroxylamine hydrochloride; sodium acetate; hydrogen cation; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; benzenesulfenyl chloride; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; 1: Etherification / 2: Acylation / 3: Oxidation / 4: Condensation / 5: Acylation / 6: Substitution / 7: Etherification;

Reference yield:

ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside (20701-61-5,56119-28-9,131564-36-8,142924-31-0,151123-92-1,141899-53-8) → C51H61NO13 (318954-61-9)

Guidance literature:

Multi-step reaction with 6 steps

1: 85 percent / PFL / tetrahydrofuran / 60 °C / Enzymatic reaction

2: TFAA; DMSO; Et₃N / CH₂Cl₂

3: NH₂OH*HCl; NaOAc / ethanol / 50 °C

4: 94 percent / pyridine / 0 - 40 °C

5: PhSCl; 2,6-di-tert-butyl-4-methylpyridine; 3 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.5 h / -78 - -55 °C

6: CH₂Cl₂; diethyl ether

With pyridine; 2,6-di-tert-butyl-4-methylpyridine; 3 A molecular sieve; hydroxylamine hydrochloride; sodium acetate; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; benzenesulfenyl chloride; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; 1: Acylation / 2: Oxidation / 3: Condensation / 4: Acylation / 5: Substitution / 6: Etherification;

Reference yield:

ethyl 1-thio-β-D-glucopyranoside (7473-36-1,13533-58-9,36400-88-1,56245-60-4,73494-52-7,73804-33-8,128946-17-8,686299-00-3) → C51H61NO13 (318954-61-9)

Guidance literature:

Multi-step reaction with 7 steps

1: 95 percent / H(+) / dimethylformamide

2: 85 percent / PFL / tetrahydrofuran / 60 °C / Enzymatic reaction

3: TFAA; DMSO; Et₃N / CH₂Cl₂

4: NH₂OH*HCl; NaOAc / ethanol / 50 °C

5: 94 percent / pyridine / 0 - 40 °C

6: PhSCl; 2,6-di-tert-butyl-4-methylpyridine; 3 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.5 h / -78 - -55 °C

7: CH₂Cl₂; diethyl ether

With pyridine; 2,6-di-tert-butyl-4-methylpyridine; 3 A molecular sieve; hydroxylamine hydrochloride; sodium acetate; hydrogen cation; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; benzenesulfenyl chloride; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; 1: Etherification / 2: Acylation / 3: Oxidation / 4: Condensation / 5: Acylation / 6: Substitution / 7: Etherification;

upstream raw materials:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

C₂₅H₃₅NO₇S

benzaldehyde dimethyl acetal

ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside