2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine

Base Information

Chemical Name:2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine
CAS No.:307543-56-2
Molecular Formula:C₄₄H₅₀O₂S₈Si₂
Molecular Weight:923.579
Hs Code.:

2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-<i>b</i>][1,4]dithiine

Synonyms:

Suppliers and Price of 2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine

There total 3 articles about 2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 49638-64-4
4,5-bis(methylthio)-1,3-dithiole-2-thione

: 245738-73-2
5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one

: 307543-56-2
2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine

Guidance literature:: With triisopropyl phosphite; at 140 ℃; for 5h;
DOI:10.1039/b003041o

Reference yield:

: 245738-71-0
5,6-bis-hydroxymethyl-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione

: 307543-56-2
2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 16 h / 20 °C

2: Hg(OAc)2; AcOH / CH₂Cl₂ / 5 h / 20 °C

3: 30 percent / triisopropyl phosphite / 5 h / 140 °C

With 1H-imidazole; triisopropyl phosphite; mercury(II) diacetate; acetic acid; In dichloromethane; N,N-dimethyl-formamide; 1: silylation / 2: Hydrolysis / 3: Condensation;
DOI:10.1039/b003041o

Reference yield:

: 245738-72-1
5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione

: 307543-56-2
2-(4,5-bis-methylsulfanyl-[1,3]dithiol-2-ylidene)-5,6-bis-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine

Guidance literature:: Multi-step reaction with 2 steps

1: Hg(OAc)2; AcOH / CH₂Cl₂ / 5 h / 20 °C

2: 30 percent / triisopropyl phosphite / 5 h / 140 °C

With triisopropyl phosphite; mercury(II) diacetate; acetic acid; In dichloromethane; 1: Hydrolysis / 2: Condensation;
DOI:10.1039/b003041o