tricarbonyl[(η6-1,3-phenylene)bis(phenylmethyleneoxy)bis(trimethylsilane)]chromium

Base Information

• Chemical Name: tricarbonyl[(η6-1,3-phenylene)bis(phenylmethyleneoxy)bis(trimethylsilane)]chromium
• CAS No.: 100310-77-8
• Molecular Formula: C₂₉H₃₄CrO₅Si₂
• Molecular Weight: 570.753
• Mol file: 100310-77-8.mol

Synonyms:

Chemical Property of tricarbonyl[(η6-1,3-phenylene)bis(phenylmethyleneoxy)bis(trimethylsilane)]chromium

Chemical Property:

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Safty Information:

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Useful:

Technology Process of tricarbonyl[(η6-1,3-phenylene)bis(phenylmethyleneoxy)bis(trimethylsilane)]chromium

There total 1 articles about tricarbonyl[(η6-1,3-phenylene)bis(phenylmethyleneoxy)bis(trimethylsilane)]chromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

tricarbonyl[(η6-1,3-phenylene)bis(trimethylsilane)]chromium (60429-46-1) + benzaldehyde (100-52-7) → tricarbonyl[(η6-1,3-phenylene)bis(phenylmethyleneoxy)bis(trimethylsilane)]chromium (100310-77-8)

Guidance literature:

cesium fluoride; In N,N-dimethyl-formamide; addn. of Cr complex to CsF under N2, 20°C; successive dropwise addn. of DMF and benzaldehyde via syringe; addn. of diethyl ether; reacting, 18h; filtration; washing filtrate (H2O); drying (K2SO4); evapn. to dryness; recrystn. (n-hexane); chromy. (silica gel, dichloromethan/petroleum ether 1/5); elem. anal.;

upstream raw materials:

tricarbonyl[(η6-1,3-phenylene)bis(trimethylsilane)]chromium

benzaldehyde

Refernces