[(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3]

Base Information

Chemical Name:[(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3]
CAS No.:90505-98-9
Molecular Formula:C₂₆H₄₀MnO₂P
Molecular Weight:470.514
Hs Code.:

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Chemical Property of [(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3]

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Technology Process of [(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3]

There total 3 articles about [(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 33309-88-5
palladium⁽⁰⁾bis(tricyclohexylphosphine)

: 705283-04-1,195625-21-9
μ-chloroborylenebis(dicarbonyl(η(5)-methylcyclopentadienyl))manganese(Mn-Mn)

: 90505-98-9
[(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3]

: [(μ3-BCl)((η5-C5H4Me)Mn(CO)2)(Pd(PCy3))2)]

Guidance literature:: In benzene-d6; under Ar; a mixt. of Mn-contg. compd. (0.071 mmol) and Pd-contg. compd. (0.155 mmol) was dissolved in C6D6; after 5 d (NMR spectra studies) the react. was complete; the soln. was layered with hexanes; elem. anal.;
DOI:10.1002/zaac.200800252

Reference yield: 25.0%

: 33309-88-5
palladium⁽⁰⁾bis(tricyclohexylphosphine)

: [(η(5)-C5H4Me)Mn(CO)2]2B(CMe3) (Mn-Mn)

: 90505-98-9
[(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3]

: [μ-tert-butylborylene((η5-C5H4Me)Mn(CO)2)(palladium(P(cyclohexyl)3))2]

Guidance literature:: In benzene-d6; Schlenk technique, glovebox (under Ar), Pd(P(C6H11)3)2 (0.3 mmol) added to soln. of C(CH3)3B(C5H4CH3Mn(CO)2)2 (0.134 mmol) at room temp., reaction time was 3 weeks; solvent removed (in vac.), hexane added, sepd. by fractional crystn. andrecrystn. (hexane) at -35°C; detd. by NMR;
DOI:10.1002/anie.200601237

Reference yield:

: 33309-88-5
palladium⁽⁰⁾bis(tricyclohexylphosphine)

: [(η(5)-C5H4Me)Mn(CO)2]2B(CMe3) (Mn-Mn)

: 90505-98-9
[(η5-C5H4Me)Mn(CO)2P(cyclohexyl)3]

: [(μ3-B(t)Bu)((η5-C5H4Me)Mn(CO)2)(Pd(PCy3))2)]

Guidance literature:: In not given; under Ar; addn. of 2 equivs. of Pd-contg. compd.; according to H. Braunschweig et al. Angew. Chem. Int. Ed. 2006, 45, 4352-4355;
DOI:10.1002/zaac.200800252