Fe(P(OC₆H₅)3)2(CO)2(SO₂)

Base Information

Chemical Name:Fe(P(OC₆H₅)3)2(CO)2(SO₂)
CAS No.:72556-94-6
Molecular Formula:C₃₈H₃₀FeO₁₀P₂S
Molecular Weight:796.511
Hs Code.:

Fe(P(OC<sub>6</sub>H<sub>5</sub>)3)2(CO)2(SO<sub>2</sub>)

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Chemical Property of Fe(P(OC₆H₅)3)2(CO)2(SO₂)

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Technology Process of Fe(P(OC₆H₅)3)2(CO)2(SO₂)

There total 3 articles about Fe(P(OC₆H₅)3)2(CO)2(SO₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 66808-76-2
Fe(CO)2(η(2)-CS2)(triphenylphosphite)2

: 72556-94-6,87392-51-6,87392-52-7
Fe(CO)2(P(OC₆H₅)3)2SO₂

Guidance literature:: With SO₂; In tetrahydrofuran; Irradiation (UV/VIS); under N2, stream of SO2 gas passed through cooled soln. (0-10°C)of Fe-complex in THF under irradiation for 1-8 h; react. takes place inthe dark but is much slower; filtered, solvent removed under reduced pressure, recrystd. from THF-MeOH; elem. anal.;

Reference yield: 60.0%

: 72573-42-3
(CO)2(P(OC₆H₅)3)2FeH₂

: 72556-94-6,87392-51-6,87392-52-7
Fe(CO)2(P(OC₆H₅)3)2SO₂

Guidance literature:: With triethylamine; sulfuryl chloride; In petroleum ether; byproducts: [N(C2H5)3H]Cl; under N2; water-free and N2-satd. solvent; triethylamine added to suspn. of dihydrido-complex (30/50°C); cooled to -10°C; soln. of very carefully purified SO2Cl2 added very slowly by drops; after dissolution (8 h) warmed to room temp.; filtered; washed twice (H2O); dried over P4O10 in high vac.; slowly recrystd. at -30°C (diethyl ether); elem. anal.;

Reference yield: 54.0%

: 15526-65-5,20516-74-9
trans-tricarbonylbis(triphenylphosphite)iron

: 87392-51-6,72556-94-6,87392-52-7
Fe(P(OC₆H₅)3)2(CO)2(SO₂)

Guidance literature:: With sulfur dioxide; In benzene; byproducts: CO; Irradiation (UV/VIS); N2-atmosphere; irradiation of Fe-complex (Phillips HPR 125-W lamp, cooling in ice, 2 h), bubbling SO2 through soln. (1 h); filtration, solvent removal, recrystn.; elem. anal.;
DOI:10.1039/DT9790001789