[Au(1-[[(2-chlorophenyl)diphenyl]methyl]-1H-imidazole)(PPh₃)]PF₆

Base Information

• Chemical Name: [Au(1-[[(2-chlorophenyl)diphenyl]methyl]-1H-imidazole)(PPh₃)]PF₆
• CAS No.: 393828-29-0
• Molecular Formula: C₄₀H₃₂AuClN₂P*F₆P
• Molecular Weight: 949.065
• Mol file: 393828-29-0.mol

Synonyms:

Chemical Property of [Au(1-[[(2-chlorophenyl)diphenyl]methyl]-1H-imidazole)(PPh₃)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Au(1-[[(2-chlorophenyl)diphenyl]methyl]-1H-imidazole)(PPh₃)]PF₆

There total 1 articles about [Au(1-[[(2-chlorophenyl)diphenyl]methyl]-1H-imidazole)(PPh₃)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

potassium hexafluorophosphate (17084-13-8) + (triphenylphosphine)gold(I) chloride (14243-64-2) + clotrimazole (23593-75-1) → [Au(1-[[(2-chlorophenyl)diphenyl]methyl]-1H-imidazole)(PPh3)]PF6 (393828-29-0)

Guidance literature:

In acetonitrile; a suspn. of Au-contg. compd. (0.20 mmol) in acetonitrile was refluxed under N2 until dissolution; KPF6 (1.48 mmol) was added, refluxing for 2 h;a ligand (0.31 mmol) was added; the mixt. was stirred and refluxed for 24 h and then cooled to room temp.; the mixt. was filtered through Celite; the vol. of the solvent was reduced under N2; diethyl ether was added; cooling to -10°C overnight;the solid was filtered off, washed with water and diethyl ether, and dr ied under vac.; elem. anal.;

DOI:10.1021/ic0103087

upstream raw materials:

potassium hexafluorophosphate

(triphenylphosphine)gold(I) chloride

clotrimazole