dicarbonyl(η5-cyclopentadienyl)[(1,2-η)-4,4-bis[4-pyrrolidinophenyl]but-1-ene]iron(II) hexafluorophosphate

Base Information

• Chemical Name: dicarbonyl(η5-cyclopentadienyl)[(1,2-η)-4,4-bis[4-pyrrolidinophenyl]but-1-ene]iron(II) hexafluorophosphate
• CAS No.: 866124-56-3
• Molecular Formula: C₃₁H₃₅FeN₂O₂*F₆P
• Molecular Weight: 668.442
• Mol file: 866124-56-3.mol

Synonyms:

Chemical Property of dicarbonyl(η5-cyclopentadienyl)[(1,2-η)-4,4-bis[4-pyrrolidinophenyl]but-1-ene]iron(II) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonyl(η5-cyclopentadienyl)[(1,2-η)-4,4-bis[4-pyrrolidinophenyl]but-1-ene]iron(II) hexafluorophosphate

There total 1 articles about dicarbonyl(η5-cyclopentadienyl)[(1,2-η)-4,4-bis[4-pyrrolidinophenyl]but-1-ene]iron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

allyl(cyclopentadienyl)iron(II) dicarbonyl (38960-10-0) + CH(C6H4N(CH2)4)2(1+)*PF6(1-)=CH(C6H4N(CH2)4)2PF6 (866124-54-1) → dicarbonyl(η5-cyclopentadienyl)[(1,2-η)-4,4-bis[4-pyrrolidinophenyl]but-1-ene]iron(II) hexafluorophosphate (866124-56-3)

Guidance literature:

In dichloromethane; under exclusion of H2O, O2 and light; to soln. of benzhydrylium salt in CH2Cl2 slow addn. of CH2Cl2-soln. of Fe complex at 0°C, stirred for 4 h, allowed to warm up to room temp., stirred for 12 h; solvent removed in vac., dissolved in CH2Cl2, cooled to -30°C, during 10 min diethyl ether added by condensation, cooled to -32°C,pptn., filtration, dried in vac.; Kinetics;

DOI:10.1002/hlca.200590137

upstream raw materials:

allyl(cyclopentadienyl)iron(II) dicarbonyl

CH(C₆H₄N(CH₂)4)2⁽¹⁺⁾*PF₆^(1-)=CH(C₆H₄N(CH₂)4)2PF₆