[Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)I]

Base Information

• Chemical Name: [Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)I]
• CAS No.: 883971-00-4
• Molecular Formula: C₁₈H₂₁IN₂OPd
• Molecular Weight: 514.702
• Mol file: 883971-00-4.mol

Synonyms:

Chemical Property of [Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)I]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)I]

There total 1 articles about [Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)I] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tris(dibenzylideneacetone)dipalladium (0) + 2-IC6H4CH2N(benzyl)CH2CONMe2 (883970-99-8) → [Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)I] (883971-00-4)

Guidance literature:

In benzene; (Ar); addn. of Pd2(dba)3 to soln. of IC6H4CH2N(Bn)CH2CONMe2 in benzene; stirring for 3 ds at room temp.; filtration through Celite; washing with benzene; discarding of benzene filtrate, washing with CH2Cl2; evapn. of filtrate to dryness; elem. anal.;

DOI:10.1021/om051014m

Reference yield: 87.0%

[Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)I] (883971-00-4) + triphenylphosphine (603-35-0) + thallium(I) triflate (73491-36-8) → [Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)(PPh3)](OTf) (883971-02-6)

Guidance literature:

In tetrahydrofuran; (Ar); addn. of Tl(TfO) to soln. of Pd(C6H4N(Bn)CH2CONMe2)I in THF; stirring at room temp. for 10 min; addn. of PPh3; stirring at room temp. for 2 h; filtration; washing with THF; evapn. to dryness; trituration with mixt. of THF and benzene; filtration, washing with benzene; drying, elem. anal.;

DOI:10.1021/om051014m

upstream raw materials:

2-IC₆H₄CH₂N(benzyl)CH₂CONMe₂

Downstream raw materials:

[Pd(κ3-C,N,O-C6H4(CH2N(CH2C6H5)CH2C(O)N(Me)2)-2)(PPh3)](OTf)