dichloro-[rac-2-[(diphenylphosphino-κP)methyl]ferrocenecarboxylic acid]-(η5-pentamethylcyclopentadienyl)rhodium(III)

Base Information

• Chemical Name: dichloro-[rac-2-[(diphenylphosphino-κP)methyl]ferrocenecarboxylic acid]-(η5-pentamethylcyclopentadienyl)rhodium(III)
• CAS No.: 867061-37-8
• Molecular Formula: C₃₄H₃₆Cl₂FeO₂PRh
• Molecular Weight: 737.291
• Mol file: 867061-37-8.mol

Synonyms:

Chemical Property of dichloro-[rac-2-[(diphenylphosphino-κP)methyl]ferrocenecarboxylic acid]-(η5-pentamethylcyclopentadienyl)rhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro-[rac-2-[(diphenylphosphino-κP)methyl]ferrocenecarboxylic acid]-(η5-pentamethylcyclopentadienyl)rhodium(III)

There total 1 articles about dichloro-[rac-2-[(diphenylphosphino-κP)methyl]ferrocenecarboxylic acid]-(η5-pentamethylcyclopentadienyl)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer + rac-2-[(diphenylphosphanyl)methyl]ferrocenecarboxylic acid (867061-27-6) → dichloro-[rac-2-[(diphenylphosphino-κP)methyl]ferrocenecarboxylic acid]-(η5-pentamethylcyclopentadienyl)rhodium(III) (867061-37-8)

Guidance literature:

In dichloromethane; under Ar atm.; soln. of Rh complex in CH2Cl2 was added to soln. of rac-2-((diphenylphosphino)methyl)ferrocenecarboxylic acid in CH2Cl2; mixt. stirred at room temp. for 1 h; evapd. (vac.); residue redissolved in CH2Cl2; soln. layered (hexane); allowed to crystallized by diffusion at room temp.; crystals filtered off;washed (hexane); dried (air);

DOI:10.1016/j.jorganchem.2005.06.035

upstream raw materials:

rac-2-[(diphenylphosphanyl)methyl]ferrocenecarboxylic acid