[Re(CO)3(PPh3)(Ph2P(Se)NP(Se)Ph2-κ2Se)]

Base Information

• Chemical Name: [Re(CO)3(PPh3)(Ph2P(Se)NP(Se)Ph2-κ2Se)]
• CAS No.: 934748-47-7
• Molecular Formula: C₄₅H₃₅NO₃P₃ReSe₂
• Molecular Weight: 1074.83
• Mol file: 934748-47-7.mol

Synonyms:

Chemical Property of [Re(CO)3(PPh3)(Ph2P(Se)NP(Se)Ph2-κ2Se)]

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of [Re(CO)3(PPh3)(Ph2P(Se)NP(Se)Ph2-κ2Se)]

There total 1 articles about [Re(CO)3(PPh3)(Ph2P(Se)NP(Se)Ph2-κ2Se)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

rhenium(I) pentacarbonyl bromide (14220-21-4) + triphenylphosphine (603-35-0) + potassium bis(diphenylselenophosphoryl)amide → [Re(CO)3(PPh3)(Ph2P(Se)NP(Se)Ph2-κ2Se)] (934748-47-7)

Guidance literature:

In toluene; byproducts: KBr; (N2), Schlenk technique; mixt. of Re complex, Se compd. and PPh3 in toluene refluxed for 30 min; solvent removed (vac.), washed (hexane), dissolved in CH2Cl2, filtered, crystd. (hexane/CH2Cl2, 4°C, several d);

DOI:10.1016/j.jorganchem.2006.12.028

upstream raw materials:

rhenium(I) pentacarbonyl bromide

triphenylphosphine