PtPh₂(tris(pyridin-2-yl)methanol)

Base Information

• Chemical Name: PtPh₂(tris(pyridin-2-yl)methanol)
• CAS No.: 176216-37-8
• Molecular Formula: C₂₈H₂₃N₃OPt
• Molecular Weight: 612.59
• Mol file: 176216-37-8.mol

Synonyms:

Chemical Property of PtPh₂(tris(pyridin-2-yl)methanol)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PtPh₂(tris(pyridin-2-yl)methanol)

There total 1 articles about PtPh₂(tris(pyridin-2-yl)methanol) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

cis-{Pt2(Ph)4-bis(μ-diethyl sulphide)} (64827-26-5) + tris(2-pyridyl)methyl alcohol (73569-80-9) → PtPh2(tris(pyridin-2-yl)methanol) (156397-72-7,176216-37-8)

Guidance literature:

In benzene; N2-atmosphere; stoich. amts., warming for 5 min (dissoln., then pptn.); collection, washing (C6H6), drying in air; elem. anal.;

DOI:10.1016/0022-328X(95)05874-O

Reference yield:

diphenyl[tris(pyridin-2-yl)methanol]platinum(II) (156397-72-7,176216-37-8) → [(hydroxo)(diphenyl)[tris(pyridin-2-yl)methanol]platinum(IV)]OH*nH2O

Guidance literature:

With H₂O; In acetone; the Pt-complex is reacted in refluxing acetone containing water;

DOI:10.1016/0022-328X(94)88139-1

Reference yield:

PtPh2(tris(pyridin-2-yl)methanol) (156397-72-7,176216-37-8) + water (7732-18-5) → [Pt(OH)Ph2(tris(pyridin-2-yl)methanol)][OH] * 2 H2O

Guidance literature:

In acetone; N2-atmosphere; warming in undried Me2CO to 50°C for 2 h;

DOI:10.1016/0022-328X(95)05874-O

upstream raw materials:

cis-{Pt2(Ph)4-bis(μ-diethyl sulphide)}

tris(2-pyridyl)methyl alcohol