(E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester

Base Information

Chemical Name:(E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester
CAS No.:162398-32-5
Molecular Formula:C₂₉H₄₃NO₆S₂
Molecular Weight:565.796
Hs Code.:

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Chemical Property of (E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester

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Technology Process of (E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester

There total 2 articles about (E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-51-6,185532-71-2
benzyl alcohol

: 162398-32-5
(E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: DCC, DMPA / CH₂Cl₂ / 20 °C

2: 1.) O₃, 2.) Me₂S / 1.) CH₂Cl₂, -60 deg C, 2.) CH₂Cl₂, 20 deg C

With dimethylsulfide; 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; ozone; dicyclohexyl-carbodiimide; In dichloromethane;
DOI:10.1016/S0957-4166(00)86289-8

Reference yield:

: 35519-24-5
sorbic acid benzyl ester

: 162398-32-5
(E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) O₃, 2.) Me₂S / 1.) CH₂Cl₂, -60 deg C, 2.) CH₂Cl₂, 20 deg C

With dimethylsulfide; ozone;
DOI:10.1016/S0957-4166(00)86289-8

Reference yield:

: 162398-32-5
(E)-4-[(Z)-(R)-2,2-Bis-propylsulfanyl-1-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethylimino]-but-2-enoic acid benzyl ester

: [(2R,3S,4S,5R,6S)-6-Methoxy-7-oxo-3-propylsulfanyl-2-((4S,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-1-aza-bicyclo[3.2.0]hept-4-yl]-acetic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: Et₃N / toluene / Ambient temperature

2: 77 percent / Bu₃SnH, AIBN / toluene

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; triethylamine; In toluene;
DOI:10.1016/S0957-4166(00)86289-8