Technology Process of (3aR,3bS,4R,5S,6R,8aS)-4,5,6-Tris-benzyloxy-2,2-dioxo-hexahydro-1,3-dioxa-2λ6-thia-7a-aza-cyclopenta[a]inden-7-one
There total 8 articles about (3aR,3bS,4R,5S,6R,8aS)-4,5,6-Tris-benzyloxy-2,2-dioxo-hexahydro-1,3-dioxa-2λ6-thia-7a-aza-cyclopenta[a]inden-7-one which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 8 steps
1: 93 percent / KOH (50percent) / tetrabutylammonium iodide / H2O; CH2Cl2
2: FeCl3
3: NH3 / methanol
4: Dess Martin periodane
5: 85 percent
6: 70 percent / ruthenium carbene complex (5percent w/w) / toluene / 48 h / 110 °C
7: 1.) OsO4, N-methyl morfoline N-oxide; 2.) SOCl2 / 2.) TEA
8: NaIO4 / RuCl3 / H2O; acetonitrile; CH2Cl2
With
potassium hydroxide; sodium periodate; osmium(VIII) oxide; thionyl chloride; ammonia; iron(III) chloride; Dess-Martin periodane; 4-methylmorpholine N-oxide;
ruthenium trichloride; ruthenium carbene complex (5percent w/w); tetra-(n-butyl)ammonium iodide;
In
methanol; dichloromethane; water; toluene; acetonitrile;
DOI:10.1016/0040-4039(95)02237-6
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 1.) OsO4, N-methyl morfoline N-oxide; 2.) SOCl2 / 2.) TEA
2: NaIO4 / RuCl3 / H2O; acetonitrile; CH2Cl2
With
sodium periodate; osmium(VIII) oxide; thionyl chloride; 4-methylmorpholine N-oxide;
ruthenium trichloride;
In
dichloromethane; water; acetonitrile;
DOI:10.1016/0040-4039(95)02237-6
- Guidance literature:
-
Multi-step reaction with 5 steps
1: Dess Martin periodane
2: 85 percent
3: 70 percent / ruthenium carbene complex (5percent w/w) / toluene / 48 h / 110 °C
4: 1.) OsO4, N-methyl morfoline N-oxide; 2.) SOCl2 / 2.) TEA
5: NaIO4 / RuCl3 / H2O; acetonitrile; CH2Cl2
With
sodium periodate; osmium(VIII) oxide; thionyl chloride; Dess-Martin periodane; 4-methylmorpholine N-oxide;
ruthenium trichloride; ruthenium carbene complex (5percent w/w);
In
dichloromethane; water; toluene; acetonitrile;
DOI:10.1016/0040-4039(95)02237-6
