C₁₆H₂₁BrSSi

Base Information

• Chemical Name: C₁₆H₂₁BrSSi
• CAS No.: 1338799-59-9
• Molecular Formula: C₁₆H₂₁BrSSi
• Molecular Weight: 353.398
• Mol file: 1338799-59-9.mol

Synonyms:

Chemical Property of C₁₆H₂₁BrSSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₆H₂₁BrSSi

There total 3 articles about C₁₆H₂₁BrSSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methylthiophene (554-14-3) → C16H21BrSSi (1338799-59-9)

Guidance literature:

Multi-step reaction with 3 steps

1: bromine; acetic acid

2: hydrogenchloride; n-butyllithium; Triisopropyl borate / tetrahydrofuran; water / -78 °C

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / tetrahydrofuran; water

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; Triisopropyl borate; bromine; sodium carbonate; acetic acid; In tetrahydrofuran; water;

DOI:10.1021/ja207025x

Reference yield:

3,5-dibromo-2-methylthiophene (29421-73-6) → C16H21BrSSi (1338799-59-9)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogenchloride; n-butyllithium; Triisopropyl borate / tetrahydrofuran; water / -78 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / tetrahydrofuran; water

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; Triisopropyl borate; sodium carbonate; In tetrahydrofuran; water;

DOI:10.1021/ja207025x

Reference yield:

3-bromo-2-methylthiophene-5-boronic acid (154566-69-5) + 1-bromo-2,5-dimethyl-4-(trimethylsilyl)benzene (566181-32-6) → C16H21BrSSi (1338799-59-9)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In tetrahydrofuran; water;

DOI:10.1021/ja207025x

upstream raw materials:

2-Methylthiophene

3,5-dibromo-2-methylthiophene

3-bromo-2-methylthiophene-5-boronic acid

1-bromo-2,5-dimethyl-4-(trimethylsilyl)benzene

Downstream raw materials:

C₃₁H₂₄F₆I₂S₂

C₄₅H₃₈F₆INO₂S₂

C₅₉H₅₂F₆N₂O₄S₂

C₃₇H₄₂F₆S₂Si₂