((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate

Base Information

Chemical Name:((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate
CAS No.:42916-17-6
Molecular Formula:C₁₀H₁₀O₂*C₂₀H₃₁N
Molecular Weight:447.661
Hs Code.:

((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate

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Chemical Property of ((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate

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Technology Process of ((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate

There total 6 articles about ((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 1446-61-3,104530-67-8,1416-08-6,24564-18-9,27174-94-3,66989-22-8,87926-74-7,25512-83-8
leelamine

: 939-89-9,939-90-2,3471-10-1,5685-38-1,23020-15-7,23020-18-0,42916-14-3,48126-51-8,67528-68-1,111956-00-4,111956-01-5
(1S*,2R*)-2-phenylcyclopropane-1-carboxylic acid

: 42916-17-6
((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate

Guidance literature:: In methanol; water; Heating;
DOI:10.1021/jm1011676

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 42916-17-6
((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide / water / 20 h / 20 °C

2.1: potassium cyanide; cobalt(II) chloride hexahydrate; nickel(II) cyanide tetrahydrate; hydrogen; potassium hydroxide / toluene / 2 h / 95 °C

2.2: 48 h / 95 °C

3.1: methanol; water / Heating

With potassium cyanide; nickel(II) cyanide tetrahydrate; cobalt(II) chloride hexahydrate; N-benzyl-N,N,N-triethylammonium chloride; hydrogen; potassium hydroxide; sodium hydroxide; In methanol; water; toluene;
DOI:10.1021/jm1011676

Reference yield:

: 3234-51-3
1,1-dibromo-2-phenylcyclopropane

: 42916-17-6
((1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methanaminium (1R,2S)-2-phenylcyclopropane-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium cyanide; cobalt(II) chloride hexahydrate; nickel(II) cyanide tetrahydrate; hydrogen; potassium hydroxide / toluene / 2 h / 95 °C

1.2: 48 h / 95 °C

2.1: methanol; water / Heating

With potassium cyanide; nickel(II) cyanide tetrahydrate; cobalt(II) chloride hexahydrate; hydrogen; potassium hydroxide; In methanol; water; toluene;
DOI:10.1021/jm1011676