monochlorotris(2,6-di-t-butylphenoxo)hafnium

Base Information

• Chemical Name: monochlorotris(2,6-di-t-butylphenoxo)hafnium
• CAS No.: 83584-99-0
• Molecular Formula: C₄₂H₆₃ClHfO₃
• Molecular Weight: 829.903
• Mol file: 83584-99-0.mol

Synonyms:

Chemical Property of monochlorotris(2,6-di-t-butylphenoxo)hafnium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of monochlorotris(2,6-di-t-butylphenoxo)hafnium

There total 1 articles about monochlorotris(2,6-di-t-butylphenoxo)hafnium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hafnium tetrachloride (13499-05-3) + lithium 2,6-di-tert-butylphenolate (55894-67-2) → monochlorotris(2,6-di-t-butylphenoxo)hafnium (83584-99-0)

Guidance literature:

In not given; in benzene or Et2O; crystn. from toluene; elem. anal.;

DOI:10.1039/c39820000805

Reference yield:

monochlorotris(2,6-di-t-butylphenoxo)hafnium (83584-99-0) + methyllithium (917-54-4) → HfCH3(OC6H3(C(CH3)3)2)3

Guidance literature:

In diethyl ether; LiMe (2 equiv.) was added to a soln. of the Hf compd.; react. time 2 h; evapn., extn. with pentane;

DOI:10.1039/c39820000805

upstream raw materials:

hafnium tetrachloride

lithium 2,6-di-tert-butylphenolate