1'-p-toluyl-1-bromoferrocene

Base Information

• Chemical Name: 1'-p-toluyl-1-bromoferrocene
• CAS No.: 160435-79-0
• Molecular Formula: C₁₈H₁₅BrFeO
• Molecular Weight: 383.067
• Mol file: 160435-79-0.mol

Synonyms:

Chemical Property of 1'-p-toluyl-1-bromoferrocene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1'-p-toluyl-1-bromoferrocene

There total 1 articles about 1'-p-toluyl-1-bromoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.3%

1,1'-dibromoferrocene (1293-65-8) + 4-methyl-benzoyl chloride (874-60-2) → 1'-p-toluyl-1-bromoferrocene (160435-79-0)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; N2-atmosphere; stirring dibromoferrocene (in THF) with BuLi (in hexane) at -30°C for 30 min, addn. of toluyl chloride, stirring at -25°C for 25 min; water addn., extn. into ether, drying (Na2SO4), evapn. (reduced pressure), chromy. (Al2O3, hexane, then CH2Cl2/hexane=1:4), recrystn. (hexane/CH2Cl2=5:1);

DOI:10.1016/0022-328X(95)05813-5

upstream raw materials:

1,1'-dibromoferrocene

4-methyl-benzoyl chloride