ferrocenoyl-1,1'-di-S-trityl-DL-homocysteine methyl ester

Base Information

• Chemical Name: ferrocenoyl-1,1'-di-S-trityl-DL-homocysteine methyl ester
• CAS No.: 1061195-89-8
• Molecular Formula: C₆₀H₅₆FeN₂O₆S₂
• Molecular Weight: 1021.09
• Mol file: 1061195-89-8.mol

Synonyms:

Chemical Property of ferrocenoyl-1,1'-di-S-trityl-DL-homocysteine methyl ester

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of ferrocenoyl-1,1'-di-S-trityl-DL-homocysteine methyl ester

There total 1 articles about ferrocenoyl-1,1'-di-S-trityl-DL-homocysteine methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

1,1'-bisferrocenedicarboxylic acid + S-trityl-DL-homocysteine methyl ester → ferrocenoyl-1,1'-di-S-trityl-DL-homocysteine methyl ester (1061195-89-8)

Guidance literature:

With HBTU; (C₂H₅)3N; In triethylamine; acetonitrile; Fe complex dissolved in MeCN/(C2H5)3N, HBTU added, stirred for 15 min, NH2CH(C2H4SC(C6H5)3)CO2CH3 added along with (C2H5)3N, stirred for 24 h; dild. with EtOAc, the org. phase washed with H2O, HCl soln., H2O, aq. NaHCO3, H2O, and brine, dried (MgSO4), evapd. (vac.), flash-chromd.; obtained as an oil;

DOI:10.1016/j.jorganchem.2008.06.005