[(C₅H₅)Fe(C₅H₃⁽²⁾HC₆H₄P(C₆H₅)2)]

Base Information

• Chemical Name: [(C₅H₅)Fe(C₅H₃⁽²⁾HC₆H₄P(C₆H₅)2)]
• CAS No.: 1190849-21-8
• Molecular Formula: C₂₈H₂₃FeP
• Molecular Weight: 447.303
• Mol file: 1190849-21-8.mol

Synonyms:

Chemical Property of [(C₅H₅)Fe(C₅H₃⁽²⁾HC₆H₄P(C₆H₅)2)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅H₅)Fe(C₅H₃⁽²⁾HC₆H₄P(C₆H₅)2)]

There total 1 articles about [(C₅H₅)Fe(C₅H₃⁽²⁾HC₆H₄P(C₆H₅)2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

lithium aluminium deuteride + [(C5H5)Fe(C5H3C6H4P(C6H5)2)PdCl]2 → [(C5H5)Fe(C5H3(2)HC6H4P(C6H5)2)] (1190849-21-8)

Guidance literature:

In diethyl ether; Li salt added to a soln. of Fe complex, stirred at room temp. for 2 h; quenched with H2O, the org. layer sepd., dried (MgSO4), evapd. (vac.); 69% D;

DOI:10.1021/om9005356

Reference yield:

sodium tetrachloropalladate(II) + [(C5H5)Fe(C5H3(2)HC6H4P(C6H5)2)] (1190849-21-8) → [(C5H5)Fe(C5H3C6H4P(C6H5)2)PdCl]2

Guidance literature:

With sodium hydroxide; In methanol; dichloromethane; water; an aq. soln. of N-acetylglycine and NaOH added to a soln. of Na2PdCl4 inMeOH, pH adjusted to 8.0 with NaOH soln., a soln. of Fe complex in MeOH /CH2Cl2 added, stirred at room temp. overnight; evapd. (vac.), the aq. residue extd. (CH2Cl2), the org. phase dried (MgSO4), filtered, evapd. (vac.); obtained crude;

DOI:10.1021/om9005356