Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester

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Chemical Name:Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester
CAS No.:847758-53-6
Molecular Formula:C₂₈H₄₂O₆
Molecular Weight:474.638
Hs Code.:

Synonyms:

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Chemical Property of Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester

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Technology Process of Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester

There total 3 articles about Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (1Z,2S,3R)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)heptyl benzoate

: 847758-53-6
Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: TiCl₄ / CH₂Cl₂ / 0.03 h / -78 °C

1.2: (i-Pr)2NEt / CH₂Cl₂ / 1.5 h / -78 °C

1.3: 20 percent / CH₂Cl₂ / 1.5 h / -78 °C

2.1: 50 mg / Me₄NBH(OAc)3; AcOH / acetonitrile / 16 h / -20 °C

3.1: FeCl₃ / CH₂Cl₂ / 0.5 h / 0 °C

4.1: 0.20 g / p-TsOH*H₂O / CH₂Cl₂ / 1 h / 0 °C

With iron(III) chloride; titanium tetrachloride; toluene-4-sulfonic acid; acetic acid; tetramethylammonium triacetoxyborohydride; In dichloromethane; acetonitrile;
DOI:10.1002/chem.200400825

Reference yield:

: 847758-49-0
Benzoic acid (2S,3R,4S,6R,7S,8S)-9-benzyloxy-1-eth-(Z)-ylidene-7-hydroxy-2,4,6,8-tetramethyl-5-oxo-3-((S)-1-phenyl-ethoxy)-nonyl ester

: 847758-53-6
Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 50 mg / Me₄NBH(OAc)3; AcOH / acetonitrile / 16 h / -20 °C

2: FeCl₃ / CH₂Cl₂ / 0.5 h / 0 °C

3: 0.20 g / p-TsOH*H₂O / CH₂Cl₂ / 1 h / 0 °C

With iron(III) chloride; toluene-4-sulfonic acid; acetic acid; tetramethylammonium triacetoxyborohydride; In dichloromethane; acetonitrile;
DOI:10.1002/chem.200400825

Reference yield:

: 847759-00-6
Benzoic acid (2S,3S,4R,5R,6R,7S,8S)-9-benzyloxy-1-eth-(Z)-ylidene-5,7-dihydroxy-2,4,6,8-tetramethyl-3-((S)-1-phenyl-ethoxy)-nonyl ester

: 847758-53-6
Benzoic acid (Z)-1-((S)-1-{(4S,5R,6R)-2,2,5-trimethyl-6-[(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-ethyl]-[1,3]dioxan-4-yl}-ethyl)-propenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: FeCl₃ / CH₂Cl₂ / 0.5 h / 0 °C

2: 0.20 g / p-TsOH*H₂O / CH₂Cl₂ / 1 h / 0 °C

With iron(III) chloride; toluene-4-sulfonic acid; In dichloromethane;
DOI:10.1002/chem.200400825