(+)-1,2,6-Hexanetriol

Base Information

• Chemical Name: (+)-1,2,6-Hexanetriol
• CAS No.: 130232-55-2
• Molecular Formula: C₆H₁₄O₃
• Molecular Weight: 134.175
• UNII: M33TV8AMTD
• Nikkaji Number: J2.518.156E
• Wikidata: Q27283418
• Mol file: 130232-55-2.mol

Synonyms:(+)-1,2,6-Hexanetriol;1,2,6-Hexanetriol, (+)-;1,2,6-Hexanetriol, (2R)-;UNII-M33TV8AMTD;M33TV8AMTD;130232-55-2;(R)-Hexane-1,2,6-triol;SCHEMBL4162036;Q27283418

Chemical Property of (+)-1,2,6-Hexanetriol

Chemical Property:

• XLogP3: -0.7
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 134.094294304
• Heavy Atom Count: 9
• Complexity: 56.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(CCO)CC(CO)O
• Isomeric SMILES: C(CCO)C[C@H](CO)O

Technology Process of (+)-1,2,6-Hexanetriol

There total 3 articles about (+)-1,2,6-Hexanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(R)-4-(2,2-dimethyl[1,3]dioxolan-4-yl)butan-1-ol (266318-67-6) → (R)-1,2,6-trihydroxyhexane (130232-55-2,112254-74-7)

Guidance literature:

With acetic acid; for 0.333333h;

DOI:10.1016/j.tetlet.2007.09.053

Reference yield:

5-Hexen-1-ol (821-41-0) → 1,2,6-hexanetriol (130232-56-3,112254-74-7) + (R)-1,2,6-trihydroxyhexane (130232-55-2,112254-74-7)

Guidance literature:

With potassium osmate(VI); (DHQD)2AQN; potassium carbonate; potassium hexacyanoferrate(III); In water; tert-butyl alcohol; Product distribution; other reactants: 1,4-bis(2-propenyl-, 5-hexenyl-, and 7-octenyloxy)benzenes, other reagents: K₃Fe(CN)6 or I₂/(DHQD)2-PHAL or (DHQD)2-PYR or (DHQD)2-AQN/K₂CO₃/K₂OsO₄*2H₂O;

DOI:10.1021/jo980844p

Reference yield:

hexane-1,2,6-triol (106-69-4,112254-74-7) → (R)-1,2,6-trihydroxyhexane (130232-55-2,112254-74-7)

Guidance literature:

DOI:10.1016/0957-4166(94)80016-2

upstream raw materials:

hexane-1,2,6-triol

5-Hexen-1-ol

(R)-4-(2,2-dimethyl[1,3]dioxolan-4-yl)butan-1-ol