[(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)]

Base Information

• Chemical Name: [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)]
• CAS No.: 1352439-25-8
• Molecular Formula: C₃₄H₃₈FeN₂OS
• Molecular Weight: 578.602
• Mol file: 1352439-25-8.mol

Synonyms:

Chemical Property of [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)]

There total 1 articles about [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + iron(II) bis(trimethylsilyl)amide (14760-22-6) + N,N'-dimesityl-2,2'-diamidophenyl sulfide (1352439-24-7) → [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)] (1352439-25-8)

Guidance literature:

In tetrahydrofuran; under N2; to a soln. of a ligand (0.10 mmol) in THF was added Fe-contg. compd. (0.05 mmol) at room temp.; stirring overnight at room temp.; the soln. was filtered; the solvent was removed, the solid was dissolvedin diethyl ether and n-hexane was added; elem. anal.;

DOI:10.1021/om201010a

Reference yield: 65.0%

tert-butylisonitrile (119072-55-8,7188-38-7) + [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)] (1352439-25-8) → [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(CNBu(t))3] (1352439-28-1)

Guidance literature:

In tetrahydrofuran; hexane; under N2; to a soln. of Fe-contg. compd. (0.10 mmol) in THF was added Bu(t)NC (0.30 mmol) in n-hexane; stirring overnight at room temp.; the soln. was filtered and the solvent was removed; the residue was dissolved in diethyl ether and n-hexane was added; slow evapn. of Et2O; elem. anal.;

DOI:10.1021/om201010a

Reference yield: 52.0%

[(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)] (1352439-25-8) + trimethylphosphane (594-09-2) → [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(trimethylphosphine)] (1352439-26-9)

Guidance literature:

In diethyl ether; hexane; under N2; to a soln. of Fe-contg. compd. (0.20 mmol) in diethyl ether was added PMe3 (0.24 mmol) in n-hexane; stirring overnight at room temp.; the soln. was filtered, the filtrate concd. and n-hexane was added; slowevapn. of Et2O; elem. anal.;

DOI:10.1021/om201010a

upstream raw materials:

tetrahydrofuran

iron(II) bis(trimethylsilyl)amide

N,N'-dimesityl-2,2'-diamidophenyl sulfide

Downstream raw materials:

[(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(trimethylphosphine)]

[(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(CNBu(t))3]

[(N,N'-dimesityl-2,2'-diamidophenyl sulfide-H)2Fe]

[(N-mesityl-o-amidobenzenethiolato)Fe(2,6-dimethylphenyl isocyanide)3]