[Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)]Cl

Base Information

• Chemical Name: [Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)]Cl
• CAS No.: 1157920-61-0
• Molecular Formula: C₄₇H₄₇N₄P₂Pd₂*Cl
• Molecular Weight: 978.157
• Mol file: 1157920-61-0.mol

Synonyms:

Chemical Property of [Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)]Cl

There total 1 articles about [Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tris(dibenzylideneacetone)dipalladium(0) chloroform complex (52522-40-4) + N,N,N',N'-tetramethylethylenediamine palladium(II) chloride (14267-08-4) + tert-butylisonitrile (119072-55-8,7188-38-7) + N,N'-bis[2-(diphenylphosphino)phenyl]formamidinate → [Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)]Cl (1157920-61-0)

Guidance literature:

In dichloromethane; (N2) to a soln. of formamidinate-compound and Pd2(dibenzylideneacetone)3*CHCl3 in CH2Cl2 were added tert-butylisocyanide and then PdCl2(N(CH3)2C2H4N(CH3)2), the mixt. was stirred at room temp. for 20 h; excess of isocyanide and CH2Cl2 were removed under reduced pressure, theresidue was dissolved in CH2Cl2, ether was added, ppt. was filtered, wa shed with ether and dried; elem. anal.;

DOI:10.1016/j.jorganchem.2008.12.039

Reference yield: 81.0%

ammonium hexafluorophosphate + [Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)]Cl (1157920-61-0) → [Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)][PF6] (1157920-68-7)

Guidance literature:

In dichloromethane; (N2) to a soln. of complex in CH2Cl2 and THF was added NH4PF6, stirred for 2 h; the solvents were removed under reduced pressure, the residue was dissolved in CH2Cl2, filtered, ppt. was washed with CH2Cl2, filtrates were reduced under reduced pressure, ether was added, ppt. was filtered, washed with ether, dried; elem. anal.;

DOI:10.1016/j.jorganchem.2008.12.039

upstream raw materials:

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

N,N,N',N'-tetramethylethylenediamine palladium(II) chloride

tert-butylisonitrile

Downstream raw materials:

[Pd2(tert-butylisocyanide)2(μ-N,N'-bis(2-(diphenylphosphino)phenyl)formamidinato)][PF6]