3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside

Base Information

• Chemical Name: 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside
• CAS No.: 1372765-68-8
• Molecular Formula: C₄₉H₆₃N₃O₂₃
• Molecular Weight: 1062.05
• Mol file: 1372765-68-8.mol

Synonyms:

Chemical Property of 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside

There total 1 articles about 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C57H67N3O22 → 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside (1372765-68-8)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / 16 h

2: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 2 h

With pyridine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;

DOI:10.1021/ja3018187

Reference yield:

CF3O3S(1-)*C33H37O10S(1+) + 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside (1372765-68-8) → 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-O-{3,6-di-O-acetyl-4-O-benzyl-2-O-[(1S)-phenyl-2-(2,3,5-trimethoxyphenylsulfanyl)ethyl]-α-D-glucopyranosyl}-α-D-glucopyranoside

Guidance literature:

In dichloromethane; at -40 - 20 ℃; for 16h; stereoselective reaction;

DOI:10.1021/ja3018187

Reference yield:

4-S-(2,3,5-trimethoxylphenyl)-2-(S)-phenyl-(3,4-di-acetyl-6-O-benzyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathianium triflate + 3-azidopropyl 2,3,4-tri-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3-di-O-acetyl-α-D-glucopyranoside (1372765-68-8) → C83H101N3O33S + C83H101N3O33S

Guidance literature:

In dichloromethane; at -40 - 20 ℃; for 16h; optical yield given as %de; stereoselective reaction;

DOI:10.1021/ja3018187