[(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]

Base Information

Chemical Name:[(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]
CAS No.:171193-81-0
Molecular Formula:BF₄*C₁₉H₂₆IrN₂O
Molecular Weight:578.446
Hs Code.:

Synonyms:

Suppliers and Price of [(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]

There total 1 articles about [(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: bis(ethylene)pentamethylcyclopentadienyl iridium

: 96845-60-2
(15)Nα-para-methoxybenzenediazonium tetrafluoroborate

: 171193-81-0
[(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]

Guidance literature:: In acetone; inert atmosphere; dropwise addn. of 1 equiv. diazonium salt to Ir-complex at -78°C (stirring), stirring for 1 h at -78°C; pptn. on hexane addn., decantation, washing (hexane), recrystn. (Me2CO/hexane, -10°C);

Reference yield: 99.0%

: 171193-81-0
[(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]

: 603-35-0
triphenylphosphine

: 171193-83-2
[(η(5)-C5Me5)Ir(PPh3)(p-(15)NNC6H4OMe)][BF4]

Guidance literature:: In ethanol; byproducts: C2H4; inert atmosphere; room temp.;

Reference yield:

: 171193-81-0
[(η(5)-C5Me5)Ir(C2H4)(p-(15)NαNC6H4OMe)][BF4]

: 7558-02-3,7758-02-3
potassium bromide

: [(η(5)-C5Me5)IrBr]2(μ-η(2)-p-(15)NNC6H4OMe)(μ-η(1)-p-(15)NNC6H4OMe)

Guidance literature:: In ethanol; byproducts: KBF4, C2H4; absence of air and moisture; equimolar amts., stirring for 4 h at room temp.; solvent removal, dissoln. in CH2Cl2, filtration, evapn., recrystn.;