gallane-tricyclohexylphosphine adduct

Base Information

Chemical Name:gallane-tricyclohexylphosphine adduct
CAS No.:141727-22-2
Molecular Formula:C₁₈H₃₃P*GaH₃
Molecular Weight:353.181
Hs Code.:

Synonyms:

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Chemical Property of gallane-tricyclohexylphosphine adduct

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Technology Process of gallane-tricyclohexylphosphine adduct

There total 4 articles about gallane-tricyclohexylphosphine adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 127972-23-0
cyclotrigallazane

: 2622-14-2
tricyclohexylphosphine

: poly(imidogallane)

: 141727-22-2
H₃Ga(tricyclohexylphosphine)

Guidance literature:: In tetrahydrofuran; byproducts: NH3; absence of air and moisture; excess phosphine, stirring at 25°C for 48 h; filtration off of HGaNH, removal of volatiles (reduced pressure); mixt. with PCy3 not sepd., detd. by IR and (1)H-NMR spectroscopy;
DOI:10.1021/ic981298l

Reference yield: 72.0%

: lithium tetrahydridogallate

: 2622-14-2
tricyclohexylphosphine

: 141727-22-2
H₃Ga(tricyclohexylphosphine)

Guidance literature:: In diethyl ether; byproducts: LiH; slow addn. of P(C6H11)3 (3.57 mmol) to soln. of LiGaH4 at -30°C with stirring; warming to room temp.;; removing ppt. by filtration; concg. mother liquor in vac.; cooling to -30°C (pptn.); elem. anal.;;

Reference yield: 50.0%

: 167962-06-3
(C₆H₁₁)3PGaH₂Cl

: 829-84-5
dicyclohexylphosphane

: 141727-22-2
H₃Ga(tricyclohexylphosphine)

: [Ga₃P₃H₆(C₆H₁₁)6]

Guidance literature:: With n-BuLi; In tetrahydrofuran; addn. of n-BuLi to HPCy2 in THF, addn. to Cy3PGaH2Cl in THF, stirring (0°C, 10 min, room temp., 24 h); filtration, concn., cooling to ca. -30°C;
DOI:10.1039/c39950001669