Ni(1,4-bis(dicyclohexylphosphino)butane)CO₂

Base Information

• Chemical Name: Ni(1,4-bis(dicyclohexylphosphino)butane)CO₂
• CAS No.: 141974-68-7
• Molecular Formula: C₂₉H₅₂NiO₂P₂
• Molecular Weight: 553.368
• Mol file: 141974-68-7.mol

Synonyms:

Chemical Property of Ni(1,4-bis(dicyclohexylphosphino)butane)CO₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(1,4-bis(dicyclohexylphosphino)butane)CO₂

There total 1 articles about Ni(1,4-bis(dicyclohexylphosphino)butane)CO₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,4-bis(dicyclohexylphosphino)butanenickel(0) (141974-63-2) → Ni(1,4-bis(dicyclohexylphosphino)butane)CO2 (141974-68-7)

Guidance literature:

With carbon dioxide; In toluene; stirred under CO2 for 10 min at room temp. and atmospheric pressure; solvent evapd. in vac., n-heptane added, precipitate washed with cold n-heptane, dried in vac., elem. anal.;

DOI:10.1016/S0020-1693(00)80758-6

Reference yield:

Ni(1,4-bis(dicyclohexylphosphino)butane)CO2 (141974-68-7) → (peroxocarbonato)1,4-bis(dicyclohexylphosphino)butanenickel(II) (141997-34-4)

Guidance literature:

With oxygen; In neat (no solvent); exposed to dry oxygen at room temp. and atmospheric pressure;

DOI:10.1016/S0020-1693(00)80758-6

upstream raw materials:

1,4-bis(dicyclohexylphosphino)butanenickel⁽⁰⁾

Downstream raw materials:

(peroxocarbonato)1,4-bis(dicyclohexylphosphino)butanenickel(II)